Concept explainers
Predict the products of each reaction and write balanced complete ionic and net ionic equations for each. If no reaction occurs, write NO REACTION.
a.
b.
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d.
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INTRODUCTORY CHEMISTRY-W/MOD.MASTERING.
- Many plants are poisonous because their stems and leaves contain oxalic acid H2C2O4, or sodium oxalate, Na2C2O4. When ingested, these substances cause swelling of the respiratory tract and suffocation. A standard analysis for determining the amount of oxalate ion, C2O42 in a sample is to precipitate this species as calcium oxalate, which is insoluble in water. Write die net ionic equation for the reaction between sodium oxalate and calcium chloride. CaCl2, in aqueous solution.arrow_forwardCitric acid, which can be obtained from lemon juice, has the molecular formula C6H8O7. A 0.250-g sample of citric acid dissolved in 25.0 mL of water requires 37.2 mL of 0.105 M NaOH for complete neutralization. What number of acidic hydrogens per molecule does citric acid have?arrow_forwardElemental bromine is the source of bromine compounds. The element is produced from certain brine solutions that occur naturally. These brines are essentially solutions of calcium bromide that, when treated with chlorine gas, yield bromine in a displacement reaction. What are the molecular equation and net ionic equation for the reaction? A solution containing 40.0 g of calcium bromide requires 14.2 g of chlorine to react completely with it, and 22.2 g of calcium chloride is produced in addition to whatever bromine is obtained. How many grams of calcium bromide are required to produce 10.0 pounds of bromine?arrow_forward
- Consider the following generic equation: H+(aq)+ B(aq)HB(aq)For which of the following pairs would this be the correct prototype equation for the acid-base reaction in solution? If it is not correct, write the proper equation for the acid-base reaction between the pair. (a) nitric acid and calcium hydroxide (b) hydrochloric acid and CH3NH2 (c) hydrobromic acid and aqueous ammonia (d) perchloric acid and barium hydroxide (e) sodium hydroxide and nitrous acidarrow_forwardLactic acid, C3H6O3 is the acid present in sour milk. A 0.100-g sample of pure lactic acid requires 12.95 mL of 0.0857 M sodium hydroxide for complete reaction. How many moles of hydroxide ion are required to neutralize one mole of lactic acid?arrow_forwardArsenic acid, H3AsO4, is a poisonous acid that has been used in the treatment of wood to prevent insect damage. Arsenic acid has three acidic protons. Say you take a 25.00-mL sample of arsenic acid and prepare it for titration with NaOH by adding 25.00 mL of water. The complete neutralization of this solution requires the addition of 53.07 mL of 0.6441 M NaOH solution. Write the balanced chemical reaction for the titration, and calculate the molarity of the arsenic acid sample.arrow_forward
- Twenty-five mL of a 0.388 M solution of Na2SO4 is mixed with 35.3 mL of 0.229 M Na2SO4. What is the molarity of the resulting solution? Assume that the volumes are additive.arrow_forwardA 1.345-g sample of a compound of barium and oxygen was dissolved in hydrochloric acid to give a solution of barium ion, which was then precipitated with an excess of potassium chromate to give 2.012 g of barium chromate, BaCrO4. What is the formula of the compound?arrow_forward1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forward
- A 0.608-g sample of fertilizer contained nitrogen as ammonium sulfate, (NH4)2SO4. It was analyzed for nitrogen by heating with sodium hydroxide. (NH4)2SO4(s)+2NaOH(aq)Na2SO4(aq)+2H2O(l)+2NH3(g) The ammonia was collected in 46.3 mL of 0.213 M HCl (hydrochloric acid), with which it reacted. NH3(g)+HCl(aq)NH4Cl(aq) This solution was titrated for excess hydrochloric acid with 44.3 mL of 0.128 M NaOH. NaOH(aq)+HCl(aq)NaCl(aq)+H2O(l) What is the percentage of nitrogen in the fertilizer?arrow_forwardChlorine gas was first prepared in 1774 by C. W. Scheele by oxidizing sodium chloride with manganese(IV) oxide. The reaction is NaCl(aq) + H2SO4(aq) + MnO2(s) Na2SO4(aq) + MnCl2(aq) + H2O(l) + Cl2 (g) Balance this equation.arrow_forwardThe Behavior of Substances in Water Part 1: a Ammonia, NH3, is a weak electrolyte. It forms ions in solution by reacting with water molecules to form the ammonium ion and hydroxide ion. Write the balanced chemical reaction for this process, including state symbols. b From everyday experience you are probably aware that table sugar (sucrose), C12H22O11, is soluble in water. When sucrose dissolves in water, it doesnt form ions through any reaction with water. It just dissolves without forming ions, so it is a nonelectrolyte. Write the chemical equation for the dissolving of sucrose in water. c Both NH3 and C12H22O11 are soluble molecular compounds, yet they behave differently in aqueous solution. Briefly explain why one is a weak electrolyte and the other is a nonelectrolyte. d Hydrochloric acid, HCl, is a molecular compound that is a strong electrolyte. Write the chemical reaction of HCl with water. e Compare the ammonia reaction with that of hydrochloric acid. Why are both of these substances considered electrolytes? f Explain why HCl is a strong electrolyte and ammonia is a weak electrolyte. g Classify each of the following substances as either ionic or molecular. KCl NH3 CO2 MgBr2 HCl Ca(OH)2 PbS HC2H3O2 h For those compounds above that you classified as ionic, use the solubility rules to determine which are soluble. i The majority of ionic substances are solids at room temperature. Describe what you would observe if you placed a soluble ionic compound and an insoluble ionic compound in separate beakers of water. j Write the chemical equation(s), including state symbols, for what happens when each soluble ionic compound that you identified above is placed in water. Are these substances reacting with water when they are added to water? k How would you classify the soluble ionic compounds: strong electrolyte, weak electrolyte, or nonelectrolyte? Explain your answer. l Sodium chloride, NaCl, is a strong electrolyte, as is hydroiodic acid, HI. Write the chemical equations for what happens when these substances are added to water. m Are NaCl and HI strong electrolytes because they have similar behavior in aqueous solution? If not, describe, using words and equations, the different chemical process that takes place in each case. Part 2: You have two hypothetical molecular compounds, AX and AY. AX is a strong electrolyte and AY is a weak electrolyte. The compounds undergo the following chemical reactions when added to water. AX(aq)+H2O(l)AH2O+(aq)+X(aq)AY(aq)+H2O(l)AH2O+(aq)+Y(aq) a Explain how the relative amounts of AX(aq) and AY(aq) would compare if you had a beaker of water with AX and a beaker of water with AY. b How would the relative amounts of X(aq) and Y(aq) in the two beakers compare? Be sure to explain your answer.arrow_forward
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