Interpretation Introduction To determine: The required energy. Explanation Given: The wavelength required is 792 nm . The volume of tube is 100.0 mL . The pressure of iodine is 55.7 mtorr . The temperature is 25.0 ∘ C . The dissociation percentage is 15 .0 % . Explanation: Convert the units of volume as follows: 100.0 mL × ( 1 L 1000 mL ) = 0.1 L Convert the units of pressure as follows: 55.7 mtorr × ( 1 torr 1000 mtorr ) × ( 1 atm 760 torr ) = 7 .33 × 10 − 5 atm Convert the units of temperature as follows: T/K = T/ ° C + 273.15 = ( 25.0 + 273.15 ) K =298 .15 K Calculate the number of moles of iodine present using the ideal gas equation as follows: P V = n R T n = P V R T = ( 7 .33 × 10 − 5 atm ) × ( 0.1 L ) ( 0.082057 L .atm .mol − 1 . K − 1 ) × 298 .15 K = 0 .02996 × 10 − 5 mol Calculate the number of molecules of iodine present as follows: N = 0 .02996 × 10 − 5 mol × ( 6

Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition

4th Edition

ISBN: 9780134554259

Author: Nivaldo J. Tro

Publisher: PEARSON

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Chapter 7, Problem 89E

Interpretation Introduction

To determine: The required energy.

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Chapter 7, Problem 88E

Chapter 7, Problem 90E

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13.84. Chlorine atoms react with methane, forming HCI and CH3. The rate constant for the reaction is 6.0 × 107 M¹ s¹ at 298 K. When the experiment was run at three other temperatures, the following data were collected: T (K) k (M-1 s-1) 303 6.5 × 107 308 7.0 × 107 313 7.5 x 107 a. Calculate the values of the activation energy and the frequency factor for the reaction. b. What is the value of the rate constant in the lower stratosphere, where T = 218 K?

Chapter 7 Solutions

Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition

Ch. 7 - Which wavelength of light has the highest...Ch. 7 - Q2. Which kind of electromagnetic radiation...Ch. 7 - Q3. How much energy (in J) is contained in 1.00...Ch. 7 - Q4. Light from three different lasers (A, B, and...Ch. 7 - Prob. 5SAQ Ch. 7 - Prob. 6SAQ Ch. 7 - Prob. 7SAQ Ch. 7 - Prob. 8SAQ Ch. 7 - Prob. 9SAQ Ch. 7 - Prob. 10SAQ

Ch. 7 - 1. Why is the quantum mechanical model of the atom...Ch. 7 - Prob. 2E Ch. 7 - 3. Define the wavelength and amplitude of a wave....Ch. 7 - 4. Define the frequency of electromagnetic...Ch. 7 - 5. What determines the color of light? Describe...Ch. 7 - Prob. 6E Ch. 7 - Prob. 7E Ch. 7 - Prob. 8E Ch. 7 - Prob. 9E Ch. 7 - 10. Describe the photoelectric effect. How did...Ch. 7 - Prob. 11E Ch. 7 - 12. What is a photon? How is the energy of a...Ch. 7 - Prob. 13E Ch. 7 - Prob. 14E Ch. 7 - Prob. 15E Ch. 7 - Prob. 16E Ch. 7 - 17. What are complementary properties? How does...Ch. 7 - Prob. 18E Ch. 7 - 19. What is a trajectory? What kind of information...Ch. 7 - Prob. 20E Ch. 7 - 21. Newton’s laws of motion are deterministic....Ch. 7 - Prob. 22E Ch. 7 - 23. What is a probability distribution map? Ch. 7 - 24. For each solution to the Schrödinger equation,...Ch. 7 - Prob. 25E Ch. 7 - 26. What is the Schrödinger equation? What is a...Ch. 7 - 27. What are the possible values of the principal...Ch. 7 - 28. What are the possible values of the angular...Ch. 7 - 29. What are the possible values of the magnetic...Ch. 7 - 30. List all the orbitals in each principal level....Ch. 7 - 31. Explain the difference between a plot showing...Ch. 7 - 32. Make sketches of the general shapes of the s,...Ch. 7 - Prob. 33E Ch. 7 - 34. Why are atoms usually portrayed as spheres...Ch. 7 - 35. The distance from the sun to Earth is km. How...Ch. 7 - Prob. 36E Ch. 7 - 37. List these types of electromagnetic radiation...Ch. 7 - 38. List these types of electromagnetic radiation...Ch. 7 - 39. Calculate the frequency of each wavelength of...Ch. 7 - Prob. 40E Ch. 7 - 41. Calculate the energy of a photon of...Ch. 7 - 42. Calculate the energy of a photon of...Ch. 7 - 43. A laser pulse with wavelength 532 nm contains...Ch. 7 - Prob. 44E Ch. 7 - 45. Determine the energy of 1 mol of photons for...Ch. 7 - 46. How much energy is contained in 1 mol of...Ch. 7 - Prob. 47E Ch. 7 - Prob. 48E Ch. 7 - Prob. 49E Ch. 7 - 50. The smallest atoms can themselves exhibit...Ch. 7 - 51. What is the de Broglie wavelength of an...Ch. 7 - 52. A proton in a linear accelerator has a de...Ch. 7 - 53. Calculate the de Broglie wavelength of a 143-g...Ch. 7 - 54. A 0.22-caliber handgun fires a 1.9-g bullet at...Ch. 7 - 55. An electron has an uncertainty in its position...Ch. 7 - 56. An electron traveling at 3.7 × 105 m/s has an...Ch. 7 - 57. Which electron is, on average, closer to the...Ch. 7 - Prob. 58E Ch. 7 - 59. What are the possible values of l for each...Ch. 7 - Prob. 60E Ch. 7 - 61. Which set of quantum numbers cannot specify an...Ch. 7 - 62. Which combinations of n and l represent real...Ch. 7 - 63. Sketch the 1s and 2p orbitals. How do the 2s...Ch. 7 - Prob. 64E Ch. 7 - 65. An electron in a hydrogen atom is excited with...Ch. 7 - 66. Determine whether each transition in the...Ch. 7 - 67. According to the quantum-mechanical model for...Ch. 7 - 68. According to the quantum-mechanical model for...Ch. 7 - 69. Calculate the wavelength of the light emitted...Ch. 7 - 70. Calculate the frequency of the light emitted...Ch. 7 - 71. An electron in the n = 7 level of the hydrogen...Ch. 7 - Prob. 72E Ch. 7 - 73. Ultraviolet radiation and radiation of shorter...Ch. 7 - Prob. 74E Ch. 7 - Prob. 75E Ch. 7 - 76. A green leaf has a surface area of 2.50 cm2....Ch. 7 - 77. In a technique used for surface analysis...Ch. 7 - Prob. 78E Ch. 7 - Prob. 79E Ch. 7 - 80. The energy required to ionize sodium is 496...Ch. 7 - Prob. 81E Ch. 7 - 82. Suppose that, in an alternate universe, the...Ch. 7 - Prob. 83E Ch. 7 - Prob. 84E Ch. 7 - 85. The binding energy of electrons in a metal is...Ch. 7 - 86. In order for a thermonuclear fusion reaction...Ch. 7 - Prob. 87E Ch. 7 - 88. The distance from Earth to the sun is 1.5 ×...Ch. 7 - 89. The iodine molecule can be photodissociated...Ch. 7 - 90. A 5.00-mL ampule of a 0.100-M solution of...Ch. 7 - 91. A laser produces 20.0 mW of red light. In 1.00...Ch. 7 - Prob. 92E Ch. 7 - 93. The quantum yield of light-induced chemical...Ch. 7 - Prob. 94E Ch. 7 - Prob. 95E Ch. 7 - Prob. 96E Ch. 7 - Prob. 97E Ch. 7 - Prob. 98E Ch. 7 - 99. Find the velocity of an electron emitted by a...Ch. 7 - 100. Water is exposed to infrared radiation of...Ch. 7 - 101. The 2005 Nobel Prize in Physics was given, in...Ch. 7 - 102. A metal with a threshold frequency of 6.71 ×...Ch. 7 - Prob. 103E Ch. 7 - Prob. 104E Ch. 7 - 105. Explain the difference between the Bohr model...Ch. 7 - 106. The light emitted from one of the following...Ch. 7 - Prob. 107E Ch. 7 - Prob. 108E Ch. 7 - 109. Discuss the nature of light with your group....Ch. 7 - Prob. 110QGW Ch. 7 - Prob. 111QGW Ch. 7 - Prob. 112QGW Ch. 7 - Prob. 113QGW Ch. 7 - 114. On average sunlight shines on the surface of...

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