Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134162485
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 7, Problem 84E
Interpretation Introduction
To Assign: The wavelengths to transitions in the hydrogen atom.
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Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
Chapter 7 Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Ch. 7 - Which wavelength of light has the highest...Ch. 7 - Q2. Which kind of electromagnetic radiation...Ch. 7 - Q3. How much energy (in J) is contained in 1.00...Ch. 7 - Q4. Light from three different lasers (A, B, and...Ch. 7 - Prob. 5SAQCh. 7 - Prob. 6SAQCh. 7 - Prob. 7SAQCh. 7 - Prob. 8SAQCh. 7 - Prob. 9SAQCh. 7 - Prob. 10SAQ
Ch. 7 - 1. Why is the quantum mechanical model of the atom...Ch. 7 - Prob. 2ECh. 7 - 3. Define the wavelength and amplitude of a wave....Ch. 7 - 4. Define the frequency of electromagnetic...Ch. 7 - 5. What determines the color of light? Describe...Ch. 7 - Prob. 6ECh. 7 - Prob. 7ECh. 7 - Prob. 8ECh. 7 - Prob. 9ECh. 7 - 10. Describe the photoelectric effect. How did...Ch. 7 - Prob. 11ECh. 7 - 12. What is a photon? How is the energy of a...Ch. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Prob. 16ECh. 7 - 17. What are complementary properties? How does...Ch. 7 - Prob. 18ECh. 7 - 19. What is a trajectory? What kind of information...Ch. 7 - Prob. 20ECh. 7 - 21. Newton’s laws of motion are deterministic....Ch. 7 - Prob. 22ECh. 7 - 23. What is a probability distribution map?
Ch. 7 - 24. For each solution to the Schrödinger equation,...Ch. 7 - Prob. 25ECh. 7 - 26. What is the Schrödinger equation? What is a...Ch. 7 - 27. What are the possible values of the principal...Ch. 7 - 28. What are the possible values of the angular...Ch. 7 - 29. What are the possible values of the magnetic...Ch. 7 - 30. List all the orbitals in each principal level....Ch. 7 - 31. Explain the difference between a plot showing...Ch. 7 - 32. Make sketches of the general shapes of the s,...Ch. 7 - Prob. 33ECh. 7 - 34. Why are atoms usually portrayed as spheres...Ch. 7 - 35. The distance from the sun to Earth is km. How...Ch. 7 - Prob. 36ECh. 7 - 37. List these types of electromagnetic radiation...Ch. 7 - 38. List these types of electromagnetic radiation...Ch. 7 - 39. Calculate the frequency of each wavelength of...Ch. 7 - Prob. 40ECh. 7 - 41. Calculate the energy of a photon of...Ch. 7 - 42. Calculate the energy of a photon of...Ch. 7 - 43. A laser pulse with wavelength 532 nm contains...Ch. 7 - Prob. 44ECh. 7 - 45. Determine the energy of 1 mol of photons for...Ch. 7 - 46. How much energy is contained in 1 mol of...Ch. 7 - Prob. 47ECh. 7 - Prob. 48ECh. 7 - Prob. 49ECh. 7 - 50. The smallest atoms can themselves exhibit...Ch. 7 - 51. What is the de Broglie wavelength of an...Ch. 7 - 52. A proton in a linear accelerator has a de...Ch. 7 - 53. Calculate the de Broglie wavelength of a 143-g...Ch. 7 - 54. A 0.22-caliber handgun fires a 1.9-g bullet at...Ch. 7 - 55. An electron has an uncertainty in its position...Ch. 7 - 56. An electron traveling at 3.7 × 105 m/s has an...Ch. 7 - 57. Which electron is, on average, closer to the...Ch. 7 - Prob. 58ECh. 7 - 59. What are the possible values of l for each...Ch. 7 - Prob. 60ECh. 7 - 61. Which set of quantum numbers cannot specify an...Ch. 7 - 62. Which combinations of n and l represent real...Ch. 7 - 63. Sketch the 1s and 2p orbitals. How do the 2s...Ch. 7 - Prob. 64ECh. 7 - 65. An electron in a hydrogen atom is excited with...Ch. 7 - 66. Determine whether each transition in the...Ch. 7 - 67. According to the quantum-mechanical model for...Ch. 7 - 68. According to the quantum-mechanical model for...Ch. 7 - 69. Calculate the wavelength of the light emitted...Ch. 7 - 70. Calculate the frequency of the light emitted...Ch. 7 - 71. An electron in the n = 7 level of the hydrogen...Ch. 7 - Prob. 72ECh. 7 - 73. Ultraviolet radiation and radiation of shorter...Ch. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - 76. A green leaf has a surface area of 2.50 cm2....Ch. 7 - 77. In a technique used for surface analysis...Ch. 7 - Prob. 78ECh. 7 - Prob. 79ECh. 7 - 80. The energy required to ionize sodium is 496...Ch. 7 - Prob. 81ECh. 7 - 82. Suppose that, in an alternate universe, the...Ch. 7 - Prob. 83ECh. 7 - Prob. 84ECh. 7 - 85. The binding energy of electrons in a metal is...Ch. 7 - 86. In order for a thermonuclear fusion reaction...Ch. 7 - Prob. 87ECh. 7 - 88. The distance from Earth to the sun is 1.5 ×...Ch. 7 - 89. The iodine molecule can be photodissociated...Ch. 7 - 90. A 5.00-mL ampule of a 0.100-M solution of...Ch. 7 - 91. A laser produces 20.0 mW of red light. In 1.00...Ch. 7 - Prob. 92ECh. 7 - 93. The quantum yield of light-induced chemical...Ch. 7 - Prob. 94ECh. 7 - Prob. 95ECh. 7 - Prob. 96ECh. 7 - Prob. 97ECh. 7 - Prob. 98ECh. 7 - 99. Find the velocity of an electron emitted by a...Ch. 7 - 100. Water is exposed to infrared radiation of...Ch. 7 - 101. The 2005 Nobel Prize in Physics was given, in...Ch. 7 - 102. A metal with a threshold frequency of 6.71 ×...Ch. 7 - Prob. 103ECh. 7 - Prob. 104ECh. 7 - 105. Explain the difference between the Bohr model...Ch. 7 - 106. The light emitted from one of the following...Ch. 7 - Prob. 107ECh. 7 - Prob. 108ECh. 7 - 109. Discuss the nature of light with your group....Ch. 7 - Prob. 110QGWCh. 7 - Prob. 111QGWCh. 7 - Prob. 112QGWCh. 7 - Prob. 113QGWCh. 7 - 114. On average sunlight shines on the surface of...
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