Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134162485
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 7, Problem 31E
Interpretation Introduction
To explain: The difference between the two plots of radial distribution and probability density.
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Primary, Secondary, and
Tertiary Alcohols
O-H
O-H
O-H
R₁-C-H
R₁-C-H
R₁-C-R₁
H
R₂
R₂
Primary
Alcohol
Secondary
Alcohol
ChemistryLearner.com
R stands for Carbon group like ethyl methyl propyl
Tertiary
Alcohol
If 1 carbon group with two H attached to alcoholic carbon, then primary
If 2 carbon group and 1 H are attached to alcoholic carbon, then secondary
IF 3 carbon group and no H attach to alcoholic carbon then tertiary.
The bottom line
Starting
"Weak" oxidant
material
PCC, DMP, Swern, etc
Primary alcohol
Aldehyde
OH
Secondary alcohol
Ketone
OH
"Strong" oxidant
KMnO4, H₂CrO4
(or equivalent)
OH
Carboxylic acid
요
Ketone
No reaction
No reaction
Tertiary alcohol
1. Is ethanol a primary, secondary, or tertiary alcohol? Write out the
structures of
ethanol and any oxidation products of ethanol. If there is more than one
oxidation product, give the structure of each of the products.
2. Is 2-propanol a primary, secondary, or tertiary alcohol? Write out the
structures of
2-propanol and any…
Formulate the reaction: Naphthalene with CrO3 in acetic acid at 25ºC
Complete the reaction
hand written please
Chapter 7 Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Ch. 7 - Which wavelength of light has the highest...Ch. 7 - Q2. Which kind of electromagnetic radiation...Ch. 7 - Q3. How much energy (in J) is contained in 1.00...Ch. 7 - Q4. Light from three different lasers (A, B, and...Ch. 7 - Prob. 5SAQCh. 7 - Prob. 6SAQCh. 7 - Prob. 7SAQCh. 7 - Prob. 8SAQCh. 7 - Prob. 9SAQCh. 7 - Prob. 10SAQ
Ch. 7 - 1. Why is the quantum mechanical model of the atom...Ch. 7 - Prob. 2ECh. 7 - 3. Define the wavelength and amplitude of a wave....Ch. 7 - 4. Define the frequency of electromagnetic...Ch. 7 - 5. What determines the color of light? Describe...Ch. 7 - Prob. 6ECh. 7 - Prob. 7ECh. 7 - Prob. 8ECh. 7 - Prob. 9ECh. 7 - 10. Describe the photoelectric effect. How did...Ch. 7 - Prob. 11ECh. 7 - 12. What is a photon? How is the energy of a...Ch. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Prob. 16ECh. 7 - 17. What are complementary properties? How does...Ch. 7 - Prob. 18ECh. 7 - 19. What is a trajectory? What kind of information...Ch. 7 - Prob. 20ECh. 7 - 21. Newton’s laws of motion are deterministic....Ch. 7 - Prob. 22ECh. 7 - 23. What is a probability distribution map?
Ch. 7 - 24. For each solution to the Schrödinger equation,...Ch. 7 - Prob. 25ECh. 7 - 26. What is the Schrödinger equation? What is a...Ch. 7 - 27. What are the possible values of the principal...Ch. 7 - 28. What are the possible values of the angular...Ch. 7 - 29. What are the possible values of the magnetic...Ch. 7 - 30. List all the orbitals in each principal level....Ch. 7 - 31. Explain the difference between a plot showing...Ch. 7 - 32. Make sketches of the general shapes of the s,...Ch. 7 - Prob. 33ECh. 7 - 34. Why are atoms usually portrayed as spheres...Ch. 7 - 35. The distance from the sun to Earth is km. How...Ch. 7 - Prob. 36ECh. 7 - 37. List these types of electromagnetic radiation...Ch. 7 - 38. List these types of electromagnetic radiation...Ch. 7 - 39. Calculate the frequency of each wavelength of...Ch. 7 - Prob. 40ECh. 7 - 41. Calculate the energy of a photon of...Ch. 7 - 42. Calculate the energy of a photon of...Ch. 7 - 43. A laser pulse with wavelength 532 nm contains...Ch. 7 - Prob. 44ECh. 7 - 45. Determine the energy of 1 mol of photons for...Ch. 7 - 46. How much energy is contained in 1 mol of...Ch. 7 - Prob. 47ECh. 7 - Prob. 48ECh. 7 - Prob. 49ECh. 7 - 50. The smallest atoms can themselves exhibit...Ch. 7 - 51. What is the de Broglie wavelength of an...Ch. 7 - 52. A proton in a linear accelerator has a de...Ch. 7 - 53. Calculate the de Broglie wavelength of a 143-g...Ch. 7 - 54. A 0.22-caliber handgun fires a 1.9-g bullet at...Ch. 7 - 55. An electron has an uncertainty in its position...Ch. 7 - 56. An electron traveling at 3.7 × 105 m/s has an...Ch. 7 - 57. Which electron is, on average, closer to the...Ch. 7 - Prob. 58ECh. 7 - 59. What are the possible values of l for each...Ch. 7 - Prob. 60ECh. 7 - 61. Which set of quantum numbers cannot specify an...Ch. 7 - 62. Which combinations of n and l represent real...Ch. 7 - 63. Sketch the 1s and 2p orbitals. How do the 2s...Ch. 7 - Prob. 64ECh. 7 - 65. An electron in a hydrogen atom is excited with...Ch. 7 - 66. Determine whether each transition in the...Ch. 7 - 67. According to the quantum-mechanical model for...Ch. 7 - 68. According to the quantum-mechanical model for...Ch. 7 - 69. Calculate the wavelength of the light emitted...Ch. 7 - 70. Calculate the frequency of the light emitted...Ch. 7 - 71. An electron in the n = 7 level of the hydrogen...Ch. 7 - Prob. 72ECh. 7 - 73. Ultraviolet radiation and radiation of shorter...Ch. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - 76. A green leaf has a surface area of 2.50 cm2....Ch. 7 - 77. In a technique used for surface analysis...Ch. 7 - Prob. 78ECh. 7 - Prob. 79ECh. 7 - 80. The energy required to ionize sodium is 496...Ch. 7 - Prob. 81ECh. 7 - 82. Suppose that, in an alternate universe, the...Ch. 7 - Prob. 83ECh. 7 - Prob. 84ECh. 7 - 85. The binding energy of electrons in a metal is...Ch. 7 - 86. In order for a thermonuclear fusion reaction...Ch. 7 - Prob. 87ECh. 7 - 88. The distance from Earth to the sun is 1.5 ×...Ch. 7 - 89. The iodine molecule can be photodissociated...Ch. 7 - 90. A 5.00-mL ampule of a 0.100-M solution of...Ch. 7 - 91. A laser produces 20.0 mW of red light. In 1.00...Ch. 7 - Prob. 92ECh. 7 - 93. The quantum yield of light-induced chemical...Ch. 7 - Prob. 94ECh. 7 - Prob. 95ECh. 7 - Prob. 96ECh. 7 - Prob. 97ECh. 7 - Prob. 98ECh. 7 - 99. Find the velocity of an electron emitted by a...Ch. 7 - 100. Water is exposed to infrared radiation of...Ch. 7 - 101. The 2005 Nobel Prize in Physics was given, in...Ch. 7 - 102. A metal with a threshold frequency of 6.71 ×...Ch. 7 - Prob. 103ECh. 7 - Prob. 104ECh. 7 - 105. Explain the difference between the Bohr model...Ch. 7 - 106. The light emitted from one of the following...Ch. 7 - Prob. 107ECh. 7 - Prob. 108ECh. 7 - 109. Discuss the nature of light with your group....Ch. 7 - Prob. 110QGWCh. 7 - Prob. 111QGWCh. 7 - Prob. 112QGWCh. 7 - Prob. 113QGWCh. 7 - 114. On average sunlight shines on the surface of...
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