EP ORGANIC CHEMISTRY-OWL V2 ACCESS
EP ORGANIC CHEMISTRY-OWL V2 ACCESS
8th Edition
ISBN: 9781305582453
Author: Brown
Publisher: Cengage Learning
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Chapter 7, Problem 7.9P
Interpretation Introduction

Interpretation:

For the given equilibrium reaction, the ratio between more stable isomer to less stable isomer has to be calculated.

Concept Introduction:

Standard reaction Gibbs energy and equilibrium constant:

The relationship between Gibbs energy and equilibrium constant is given by,

  ΔrGo=-RTlnKwhere, ΔrGo-standardreactionGibbsenergy R-gasconstant T-temperatureandK-equilibriumconstant

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∆H° values obtained for a series of similar reactions are one set of experimental data used to determine the relative stability of alkenes. Explain how the following data suggest that cis-but-2-ene is more stable than but-1-ene (Section 12.3A).
Mark the correct statements about the structural features of alkenes and alkynes. *         A- Free rotation is not possible around a double or triple bond.         B- A triple bond is shorter and stronger than a double bond.         C- A pi-bond can only form by overlap of p-orbitals on adjacent atoms if these atoms are from the same element.         D- The pi-bond in an alkene is weaker than the sigma bond because the sideways overlap of p-orbitals is less than the head-to-head overlap of sp² hybrid orbitals.         E- All the bond angles in an alkyne are 180°.
draw structural formulas for all isomeric alkanes with molecular formula C7H16. Predict which isomer has the lowest boiling point and which has the highest boiling point.

Chapter 7 Solutions

EP ORGANIC CHEMISTRY-OWL V2 ACCESS

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