Among liquid bromine and the interhalogen compound, the compound having higher boiling point should be identified. Also the reason for the difference in boiling point should be stated. Concept introduction: The set of repulsive and attractive force between molecules that result from the polarity between neighboring molecules is represented as intermolecular force. There are four types of intermolecular forces: Hydrogen bonding London dispersion force Ion – dipole force Dipole – Dipole force Ion – dipole force is a strong intermolecular force as it contains both ionic and polar bonds. Hydrogen bond: Hydrogen is bonded to strong electronegative atom like oxygen, nitrogen etc. Dipole – Dipole: This force takes place between two polar compounds. London dispersion force: This force is present in all compounds and is a weak force.
Among liquid bromine and the interhalogen compound, the compound having higher boiling point should be identified. Also the reason for the difference in boiling point should be stated. Concept introduction: The set of repulsive and attractive force between molecules that result from the polarity between neighboring molecules is represented as intermolecular force. There are four types of intermolecular forces: Hydrogen bonding London dispersion force Ion – dipole force Dipole – Dipole force Ion – dipole force is a strong intermolecular force as it contains both ionic and polar bonds. Hydrogen bond: Hydrogen is bonded to strong electronegative atom like oxygen, nitrogen etc. Dipole – Dipole: This force takes place between two polar compounds. London dispersion force: This force is present in all compounds and is a weak force.
Solution Summary: The author explains that liquid bromine and the interhalogen compound have higher boiling points due to the difference in electronegativity.
Interpretation: Among liquid bromine and the interhalogen compound, the compound having higher boiling point should be identified. Also the reason for the difference in boiling point should be stated.
Concept introduction: The set of repulsive and attractive force between molecules that result from the polarity between neighboring molecules is represented as intermolecular force. There are four types of intermolecular forces:
Hydrogen bonding
London dispersion force
Ion – dipole force
Dipole – Dipole force
Ion – dipole force is a strong intermolecular force as it contains both ionic and polar bonds.
Hydrogen bond: Hydrogen is bonded to strong electronegative atom like oxygen, nitrogen etc.
Dipole – Dipole: This force takes place between two polar compounds.
London dispersion force: This force is present in all compounds and is a weak force.
An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.
The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?
One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.
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