CHEMISTRY:ATOMS FIRST (LL)>CUSTOM PKG.<
2nd Edition
ISBN: 9781259382307
Author: Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 7, Problem 7.70QP
What is molecular orbital theory? How does it differ from
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Transmitance
3. Which one of the following compounds corresponds to
this IR spectrum?
Point out the absorption band(s) that helped you
decide.
OH
H3C
OH
H₂C
CH3
H3C
CH3
H3C
INFRARED SPECTRUM
0.8-
0.6
0.4-
0.2
3000
2000
1000
Wavenumber (cm-1)
4. Consider this compound:
H3C
On the structure above, label the different types of H's
as A, B, C, etc.
In table form, list the labeled signals, and for each
one state the number of hydrogens, their shifts, and the
splitting you would observe for these hydrogens in the ¹H
NMR spectrum.
Label
# of hydrogens
splitting
Shift (2)
Chapter 7 Solutions
CHEMISTRY:ATOMS FIRST (LL)>CUSTOM PKG.<
Ch. 7.1 - Determine the shapes of (a) SO3 and (b) ICl4.Ch. 7.1 - Determine the shapes of (a) CO2 and (b) SCl2.Ch. 7.1 - (a) From what group must the terminal atoms come...Ch. 7.1 - These four models may represent molecules or...Ch. 7.1 - Acetic acid, the substance that gives vinegar its...Ch. 7.1 - Ethanolamine (HOCH2CH2NH2) has a smell similar to...Ch. 7.1 - The bond angle in NH3 is significantly smaller...Ch. 7.1 - Which of these models represents a species in...Ch. 7.1 - Prob. 7.1.1SRCh. 7.1 - Prob. 7.1.2SR
Ch. 7.1 - Prob. 7.1.3SRCh. 7.1 - Prob. 7.1.4SRCh. 7.2 - Prob. 7.3WECh. 7.2 - Prob. 3PPACh. 7.2 - For each of the following hypothetical molecules,...Ch. 7.2 - Which of these models could represent a polar...Ch. 7.2 - Prob. 7.2.1SRCh. 7.2 - Prob. 7.2.2SRCh. 7.3 - Prob. 7.4WECh. 7.3 - Prob. 4PPACh. 7.3 - Prob. 4PPBCh. 7.3 - Prob. 4PPCCh. 7.3 - Prob. 7.3.1SRCh. 7.3 - Prob. 7.3.2SRCh. 7.4 - Hydrogen selenide (H2Se) is a foul-smelling gas...Ch. 7.4 - Prob. 5PPACh. 7.4 - For which molecule(s) can we not use valence bond...Ch. 7.4 - Which of these models could represent a species...Ch. 7.4 - Prob. 7.4.1SRCh. 7.4 - Prob. 7.4.2SRCh. 7.5 - Prob. 7.6WECh. 7.5 - Use hybrid orbital theory to describe the bonding...Ch. 7.5 - Prob. 6PPBCh. 7.5 - Prob. 6PPCCh. 7.5 - Prob. 7.5.1SRCh. 7.5 - Prob. 7.5.2SRCh. 7.6 - Thalidomide (C13H10N2O4) is a sedative and...Ch. 7.6 - The active ingredient in Tylenol and a host of...Ch. 7.6 - Determine the total number of sigma and pi bonds...Ch. 7.6 - In terms of valence bond theory and hybrid...Ch. 7.6 - In addition to its rise in aqueous solution as a...Ch. 7.6 - Use valence bond theory and hybrid orbitals to...Ch. 7.6 - Use valence bond theory and hybrid orbitals to...Ch. 7.6 - Explain why hybrid orbitals are necessary to...Ch. 7.6 - Prob. 7.6.1SRCh. 7.6 - Prob. 7.6.2SRCh. 7.6 - Prob. 7.6.3SRCh. 7.6 - Prob. 7.6.4SRCh. 7.7 - Prob. 7.9WECh. 7.7 - Use molecular orbital theory to determine whether...Ch. 7.7 - Use molecular orbital theory to determine whether...Ch. 7.7 - For most of the homonuclear diatomic species shown...Ch. 7.7 - Prob. 7.7.1SRCh. 7.7 - Prob. 7.7.2SRCh. 7.7 - Prob. 7.7.3SRCh. 7.7 - Prob. 7.7.4SRCh. 7.8 - It takes three resonance structures to represent...Ch. 7.8 - Use a combination of valence bond theory and...Ch. 7.8 - Use a combination of valence bond theory and...Ch. 7.8 - Prob. 10PPCCh. 7.8 - Prob. 7.8.1SRCh. 7.8 - Prob. 7.8.2SRCh. 7.8 - Prob. 7.8.3SRCh. 7.8 - Prob. 7.8.4SRCh. 7 - Prob. 7.1QPCh. 7 - Sketch the shape of a linear triatomic molecule, a...Ch. 7 - Prob. 7.3QPCh. 7 - Prob. 7.4QPCh. 7 - In the trigonal bipyramidal arrangement, why does...Ch. 7 - Prob. 7.6QPCh. 7 - Predict the geometry of the following molecules...Ch. 7 - Prob. 7.8QPCh. 7 - Predict the geometries of the following species...Ch. 7 - Predict the geometries of the following ions: (a)...Ch. 7 - Prob. 7.11QPCh. 7 - Prob. 7.12QPCh. 7 - Prob. 7.13QPCh. 7 - Describe the geometry about each of the central...Ch. 7 - Prob. 7.15QPCh. 7 - Prob. 7.16QPCh. 7 - Prob. 7.17QPCh. 7 - Prob. 7.18QPCh. 7 - Prob. 7.19QPCh. 7 - Prob. 7.20QPCh. 7 - Prob. 7.21QPCh. 7 - Prob. 7.22QPCh. 7 - Explain the term polarizability. What kind of...Ch. 7 - Prob. 7.24QPCh. 7 - What physical properties are determined by the...Ch. 7 - Prob. 7.26QPCh. 7 - Describe the types of intermolecular forces that...Ch. 7 - The compounds Br2 and ICl are isoelectronic (have...Ch. 7 - If you lived in Alaska, which of the following...Ch. 7 - The binary hydrogen compounds of the Group 4A...Ch. 7 - List the types of intermolecular forces that exist...Ch. 7 - Prob. 7.32QPCh. 7 - Prob. 7.33QPCh. 7 - Prob. 7.34QPCh. 7 - Diethyl ether has a boiling point of 34.5C, and...Ch. 7 - Prob. 7.36QPCh. 7 - Which substance in each of the following pairs...Ch. 7 - Prob. 7.38QPCh. 7 - What kind of attractive forces must be overcome to...Ch. 7 - Prob. 7.40QPCh. 7 - Prob. 7.41QPCh. 7 - The following compounds have the same molecular...Ch. 7 - Prob. 7.43QPCh. 7 - Prob. 7.44QPCh. 7 - Use valence bond theory to explain the bonding in...Ch. 7 - Prob. 7.46QPCh. 7 - Prob. 7.47QPCh. 7 - Prob. 7.48QPCh. 7 - Prob. 7.49QPCh. 7 - What is the hybridization of atomic orbitals? Why...Ch. 7 - Prob. 7.51QPCh. 7 - Prob. 7.52QPCh. 7 - Prob. 7.53QPCh. 7 - Describe the bonding scheme of the AsH3 molecule...Ch. 7 - Prob. 7.55QPCh. 7 - Prob. 7.56QPCh. 7 - Describe the hybridization of phosphorus in PF5.Ch. 7 - Prob. 7.58QPCh. 7 - Prob. 7.59QPCh. 7 - Prob. 7.1VCCh. 7 - Prob. 7.2VCCh. 7 - Prob. 7.3VCCh. 7 - Prob. 7.4VCCh. 7 - Prob. 7.60QPCh. 7 - Which of the following pairs of atomic orbitals of...Ch. 7 - Prob. 7.62QPCh. 7 - Prob. 7.63QPCh. 7 - Prob. 7.64QPCh. 7 - Prob. 7.65QPCh. 7 - Prob. 7.66QPCh. 7 - Prob. 7.67QPCh. 7 - Prob. 7.68QPCh. 7 - Benzo[a]pyrene is a potent carcinogen found in...Ch. 7 - What is molecular orbital theory? How does it...Ch. 7 - Define the following terms: bonding molecular...Ch. 7 - Prob. 7.72QPCh. 7 - Prob. 7.73QPCh. 7 - Prob. 7.74QPCh. 7 - Prob. 7.75QPCh. 7 - Draw a molecular orbital energy level diagram for...Ch. 7 - Prob. 7.77QPCh. 7 - Prob. 7.78QPCh. 7 - Prob. 7.79QPCh. 7 - Acetylene (C2H2) has a tendency to lose two...Ch. 7 - Compare the Lewis and molecular orbital treatments...Ch. 7 - Prob. 7.82QPCh. 7 - Prob. 7.83QPCh. 7 - Prob. 7.84QPCh. 7 - Prob. 7.85QPCh. 7 - Draw the molecular orbital diagram for the cyanide...Ch. 7 - Given that BeO is diamagnetic, use a molecular...Ch. 7 - Prob. 7.88QPCh. 7 - Prob. 7.89QPCh. 7 - Both ethylene (C2H4) and benzene (C6H6) contain...Ch. 7 - Chemists often represent benzene with the...Ch. 7 - Determine which of these molecules has a more...Ch. 7 - Nitryl fluoride (FNO2) is used in rocket...Ch. 7 - Describe the bonding in the nitrate ion NO3 in...Ch. 7 - Prob. 7.95QPCh. 7 - Prob. 7.96QPCh. 7 - Prob. 7.97QPCh. 7 - Prob. 7.98QPCh. 7 - Prob. 7.99QPCh. 7 - Antimony pentafluoride (SbF5) combines with XeF4...Ch. 7 - Prob. 7.101QPCh. 7 - The molecular model of nicotine (a stimulant) is...Ch. 7 - Predict the bond angles for the following...Ch. 7 - The germanium pentafluoride anion (GeF5) has been...Ch. 7 - Draw Lewis structures and give the other...Ch. 7 - Which figure best illustrates the hybridization of...Ch. 7 - Prob. 7.107QPCh. 7 - Prob. 7.108QPCh. 7 - Prob. 7.109QPCh. 7 - Prob. 7.110QPCh. 7 - Prob. 7.111QPCh. 7 - Cyclopropane (C3H6) has the shape of a triangle in...Ch. 7 - The compound 1,2-dichloroethane (C2H4Cl2) is...Ch. 7 - Prob. 7.114QPCh. 7 - Prob. 7.115QPCh. 7 - Prob. 7.116QPCh. 7 - Prob. 7.117QPCh. 7 - Prob. 7.118QPCh. 7 - The amino acid selenocysteine is one of the...Ch. 7 - Prob. 7.120QPCh. 7 - Prob. 7.121QPCh. 7 - Prob. 7.122QPCh. 7 - Gaseous or highly volatile liquid anesthetics are...Ch. 7 - Prob. 7.124QPCh. 7 - Prob. 7.125QPCh. 7 - Two of the drugs that are prescribed for the...Ch. 7 - Prob. 7.127QPCh. 7 - Prob. 7.128QPCh. 7 - The BO+ ion is paramagnetic. Determine (a) whether...Ch. 7 - Use molecular orbital theory to explain the...Ch. 7 - Which best illustrates the change in geometry...Ch. 7 - Prob. 7.132QPCh. 7 - Prob. 7.133QPCh. 7 - Aluminum trichloride (AlCl3) is an...Ch. 7 - Prob. 7.135QPCh. 7 - Prob. 7.136QPCh. 7 - Prob. 7.137QPCh. 7 - Consider an N2 molecule in its first excited...Ch. 7 - The Lewis structure for O2 is Use molecular...Ch. 7 - Draw the Lewis structure of ketene (C2H2O) and...Ch. 7 - The compound TCDD, or...Ch. 7 - Name the kinds of attractive forces that must be...Ch. 7 - Carbon monoxide (CO) is a poisonous compound due...Ch. 7 - Prob. 7.144QPCh. 7 - Prob. 7.145QPCh. 7 - Prob. 7.146QPCh. 7 - Prob. 7.147QPCh. 7 - Prob. 7.148QPCh. 7 - Prob. 7.1KSPCh. 7 - Which of the following species does not have...Ch. 7 - Prob. 7.3KSPCh. 7 - Prob. 7.4KSP
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