The role of lasers in reading a compact disc has to be explained. Concept introduction: When light of certain wavelength falls on ruby crystal (aluminum oxide contains small amount of chromium(III) ions), the chromium ions undergo transition from level one to level three . Most of Cr 3+ ions in level three undergo radiation less transition to level two by losing energy in form of heat than emitting photons. Level two has much greater lifetime which leads to accumulation of Cr 3+ ions in level three. When these accumulated ions emit all at same time an intense emission will occur. The wavelength of photon from emitted ion and original photon are same. Now there are two photons one original photon and another by stimulated emission. Finally there is increase in intensity of light at this wavelength.
The role of lasers in reading a compact disc has to be explained. Concept introduction: When light of certain wavelength falls on ruby crystal (aluminum oxide contains small amount of chromium(III) ions), the chromium ions undergo transition from level one to level three . Most of Cr 3+ ions in level three undergo radiation less transition to level two by losing energy in form of heat than emitting photons. Level two has much greater lifetime which leads to accumulation of Cr 3+ ions in level three. When these accumulated ions emit all at same time an intense emission will occur. The wavelength of photon from emitted ion and original photon are same. Now there are two photons one original photon and another by stimulated emission. Finally there is increase in intensity of light at this wavelength.
Solution Summary: The author explains the role of lasers in reading a compact disc.
The role of lasers in reading a compact disc has to be explained.
Concept introduction:
When light of certain wavelength falls on ruby crystal (aluminum oxide contains small amount of chromium(III) ions), the chromium ions undergo transition from level one to level three . Most of Cr3+ ions in level three undergo radiation less transition to level two by losing energy in form of heat than emitting photons. Level two has much greater lifetime which leads to accumulation of Cr3+ ions in level three. When these accumulated ions emit all at same time an intense emission will occur. The wavelength of photon from emitted ion and original photon are same. Now there are two photons one original photon and another by stimulated emission. Finally there is increase in intensity of light at this wavelength.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell