The given compounds should be arranged in a specific order for that which property should be considered. We have to discuss it in detail. Also, the given compound rank should be determined so that we have to arrange it in the order starting from the most ionic to least. Concept Introduction: No bond can be 100% ionic. Every ionic bond will have a small amount of covalent character in it. Such covalent character of the compounds which are ionic is described with the help of Fajan's rule. Fajan's rule states that the covalent character of a molecule gets increased by the polarization of the anion by the cation. When a cation exerts a force to distort the anion's electron cloud, it is called the polarizing power.The anion's tendency to get polarized is termed as polarisability. Hence, when there is a greater polarization, there is a more covalent character.
The given compounds should be arranged in a specific order for that which property should be considered. We have to discuss it in detail. Also, the given compound rank should be determined so that we have to arrange it in the order starting from the most ionic to least. Concept Introduction: No bond can be 100% ionic. Every ionic bond will have a small amount of covalent character in it. Such covalent character of the compounds which are ionic is described with the help of Fajan's rule. Fajan's rule states that the covalent character of a molecule gets increased by the polarization of the anion by the cation. When a cation exerts a force to distort the anion's electron cloud, it is called the polarizing power.The anion's tendency to get polarized is termed as polarisability. Hence, when there is a greater polarization, there is a more covalent character.
Solution Summary: The author explains that no bond can be 100% ionic. The polarization of the anion by the cation increases the covalent character of a molecule.
The given compounds should be arranged in a specific order for that which property should be considered. We have to discuss it in detail. Also, the given compound rank should be determined so that we have to arrange it in the order starting from the most ionic to least.
Concept Introduction:
No bond can be 100% ionic. Every ionic bond will have a small amount of covalent character in it. Such covalent character of the compounds which are ionic is described with the help of Fajan's rule. Fajan's rule states that the covalent character of a molecule gets increased by the polarization of the anion by the cation.
When a cation exerts a force to distort the anion's electron cloud, it is called the polarizing power.The anion's tendency to get polarized is termed as polarisability. Hence, when there is a greater polarization, there is a more covalent character.
Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.
An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.
Chapter 7 Solutions
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell