CHEMISTRY: AN INTRODUCTION TO GENERAL, O
13th Edition
ISBN: 9780137444298
Author: Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 7, Problem 7.82UTC
Ibuprofen, an anti-inflammatory drug in Advil, has the formula
a. What is the molar mass of ibuprofen?
b. How many grams of ibuprofen are in 0.525 mole?
c. How many moles of C are in 12.0 g of ibuprofen?
d. How many moles of ibuprofen contain
Expert Solution & Answer
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 7 Solutions
CHEMISTRY: AN INTRODUCTION TO GENERAL, O
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 200...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Quinine, C20H24N2O2 , is a component of tonic...Ch. 7.1 - Aluminum sulphate, Al2SO43 , is used in some...Ch. 7.1 - Naproxen, found in Aleve, is used to treat the...Ch. 7.1 - Benadryl is an over-the-counter drug used to treat...
Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, in 0.150 mole of...Ch. 7.3 - Calculate the mass, in grams, in 2.28 moles of...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in 25.0 g of each of...Ch. 7.3 - Calculate the number of moles in 4.00 g of each of...Ch. 7.3 - Chloroethane, C2H5Cl , is used to diagnose dead...Ch. 7.3 - Allyl sulfide, C3H52S , gives garlic, onions, and...Ch. 7.3 - a. The compound MgSO4 , Epsom salts, is used to...Ch. 7.3 - a. Cyclopropane, C3H6 , is an anesthetic given by...Ch. 7.3 - Dinitrogen oxide (or nitrous oxide), N2O , also...Ch. 7.3 - Chloroform, CHCl3 , was formerly used as an...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.5 - Prob. 7.41PPCh. 7.5 - Prob. 7.42PPCh. 7.5 - Prob. 7.43PPCh. 7.5 - Prob. 7.44PPCh. 7.6 - Prob. 7.45PPCh. 7.6 - Prob. 7.46PPCh. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - Prob. 7.49PPCh. 7.6 - Prob. 7.50PPCh. 7.6 - Prob. 7.51PPCh. 7.6 - Prob. 7.52PPCh. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - The chemical reaction of hydrogen with oxygen...Ch. 7.7 - Ammonia is produced by the chemical reaction of...Ch. 7.7 - Carbon disulfide and carbon monoxide are produced...Ch. 7.7 - In the acetylene torch, acetylene gas C2H2 burns...Ch. 7.8 - Sodium reacts with oxygen to produce sodium oxide....Ch. 7.8 - Nitrogen gas reacts with hydrogen gas to produce...Ch. 7.8 - Ammonia and oxygen react to form nitrogen and...Ch. 7.8 - Iron(III) oxide reacts with carbon to give iron...Ch. 7.8 - Nitrogen dioxide and water react to produce nitric...Ch. 7.8 - Calcium cyanamide, CaCN2 , reads with water to...Ch. 7.8 - When solid lead(II) sulfide reacts with oxygen...Ch. 7.8 - When the gases dihydrogen sulfide and oxygen...Ch. 7.9 - Prob. 7.67PPCh. 7.9 - a. What is measured by the heat of reaction? b. In...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - a. What is meant by the rate of a reaction? b. Why...Ch. 7.9 - a. How does a catalyst affect the activation...Ch. 7.9 - Prob. 7.75PPCh. 7.9 - How would each of the following change the rate of...Ch. 7.9 - a. During cellular respiration, aqueous C6H12O6...Ch. 7.9 - Fatty acids undergo reaction with oxygen gas and...Ch. 7 - Prob. 7.79UTCCh. 7 - Using the models of the molecules (black = C,...Ch. 7 - A dandruff shampoo contains dipyrithione,...Ch. 7 - Ibuprofen, an anti-inflammatory drug in Advil, has...Ch. 7 - Prob. 7.83UTCCh. 7 - Balance each of the following by adding...Ch. 7 - Prob. 7.85UTCCh. 7 - Prob. 7.86UTCCh. 7 - If blue spheres represent nitrogen atoms, purple...Ch. 7 - Prob. 7.88UTCCh. 7 - Prob. 7.89UTCCh. 7 - Prob. 7.90UTCCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - How many grams are in 0.150 mole of each of the...Ch. 7 - How many grams are in 2.25 moles of each of the...Ch. 7 - How many moles are in 25.0 g of each of the...Ch. 7 - How many moles are in 4.00 g of each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Prob. 7.99APPCh. 7 - Prob. 7.100APPCh. 7 - Identify each of the following as an oxidation or...Ch. 7 - Identify each of the following as an oxidation or...Ch. 7 - When ammonia NH3 gas reacts with fluorine gas, the...Ch. 7 - When nitrogen dioxide NO2 gas from car exhaust...Ch. 7 - Pentane gas, C5H12 undergoes combustion with...Ch. 7 - Prob. 7.106APPCh. 7 - Prob. 7.107APPCh. 7 - The equation for the formation of nitrogen oxide...Ch. 7 - Prob. 7.109CPCh. 7 - Prob. 7.110CPCh. 7 - Prob. 7.111CPCh. 7 - A toothpaste contains 0.240% by mass sodium...Ch. 7 - Prob. 7.113CPCh. 7 - Prob. 7.114CPCh. 7 - Prob. 7.115CPCh. 7 - Prob. 7.116CP
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