Student Solutions Manual for Ball's Physical Chemistry, 2nd
2nd Edition
ISBN: 9798214169019
Author: David W. Ball
Publisher: Cengage Learning US
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Chapter 7, Problem 7.73E
In February
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Indicate why boron hydrides cannot form large linear or planar structures.
Nido-boranes are structures with the molecular formula BnHn+4 that exhibit B-B, B-H-B and B-H bonds. Correct?
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9 1-(a)A sample solution was examined under XRF to quantify the analyte Ce³+. Find the response factor F, when standardized concentration of analyte [Ce³+]A =
concentration of internal standard S i.e. [In³*]s =
151
mM was spiked with standardized
1600 and As = 3015
respectively?
11
12
(i)Define F,
F =
Aa
As
[A]
[S]
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13
(*Define with variables)
4000
14
15
(ii)Calculate F,
F =
numeral
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As
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17
18
1-(b)To determine the unknown conc of analyte [Ce³+], a volume of 15 mL of internal standard S having a concentration [In³+]s =
0.264
M
19
20
was added to 45 mL of unknown, and the mixture was diluted to 100 mL in a volumetric flask. XRF analysis yielded a spectrum, Figure-1, where peak
heights A and As are…
Chapter 7 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
Ch. 7 - Prob. 7.1ECh. 7 - Prob. 7.2ECh. 7 - Prob. 7.3ECh. 7 - Prob. 7.4ECh. 7 - 7.5. For this chemical equilibrium in an enclosed...Ch. 7 - 7.6. The production of nitrogen gas for automobile...Ch. 7 - Prob. 7.7ECh. 7 - Prob. 7.8ECh. 7 - 7.9. For a solution of and in which , what are...Ch. 7 - Prob. 7.10E
Ch. 7 - Prob. 7.11ECh. 7 - Prob. 7.12ECh. 7 - Prob. 7.13ECh. 7 - 7.14. Determine the total equilibrium pressure of...Ch. 7 - Prob. 7.15ECh. 7 - 7.16. Many police departments use breath tests to...Ch. 7 - Prob. 7.17ECh. 7 - 7.18. The vapor pressures of pure liquid A and...Ch. 7 - 7.19. At , the vapor pressure of pure ethanol, ,...Ch. 7 - 7.20. A solution of methanol () and ethanol () has...Ch. 7 - 7.21. At , the vapor pressure of pure ethanol, ,...Ch. 7 - Prob. 7.22ECh. 7 - Prob. 7.23ECh. 7 - Prob. 7.24ECh. 7 - Prob. 7.25ECh. 7 - Prob. 7.26ECh. 7 - Prob. 7.27ECh. 7 - Prob. 7.28ECh. 7 - What are mixG and mixS for the combination of...Ch. 7 - Prob. 7.30ECh. 7 - Prob. 7.31ECh. 7 - Prob. 7.32ECh. 7 - Prob. 7.33ECh. 7 - Prob. 7.34ECh. 7 - Prob. 7.35ECh. 7 - Prob. 7.36ECh. 7 - Prob. 7.37ECh. 7 - Prob. 7.38ECh. 7 - Convert the units of Henrys law constant for CO2,...Ch. 7 - Prob. 7.40ECh. 7 - Prob. 7.41ECh. 7 - Prob. 7.42ECh. 7 - 7.43. The Henry’s law constant for methyl...Ch. 7 - Prob. 7.44ECh. 7 - 7.45. At , the mole fraction of air in water is...Ch. 7 - 7.45. At , the mole fraction of nitrogen, , in...Ch. 7 - Prob. 7.47ECh. 7 - 7.48. Nitrogen narcosis begins to affect scuba...Ch. 7 - Prob. 7.49ECh. 7 - 7.50. What is the approximate molarity of a...Ch. 7 - 7.51. Calculate the solubility of phenol, , in...Ch. 7 - a Convert the calculated mole fraction of...Ch. 7 - Prob. 7.53ECh. 7 - Consider the following solutions: Sodium chloride...Ch. 7 - Determine how ideal the following solutions are by...Ch. 7 - Iron metal has a fusH value of 14.9kJ/mol and is...Ch. 7 - Prob. 7.57ECh. 7 - 7.58. Do communities that use salt in the winter...Ch. 7 - 7.59. Starting from in figure in the liquid...Ch. 7 - Prob. 7.60ECh. 7 - Prob. 7.61ECh. 7 - Estimate the solubility of Na in Hg at 0C. The...Ch. 7 - Prob. 7.63ECh. 7 - Prob. 7.64ECh. 7 - Explain how the unit molarity automatically...Ch. 7 - Prob. 7.66ECh. 7 - The vapor pressure of isopropanol is 47.0mmHg at...Ch. 7 - A sample of 25.0g of solid anthracene is dissolved...Ch. 7 - Prob. 7.69ECh. 7 - A technician dissolves 12.00g of a nonvolatile...Ch. 7 - Prob. 7.71ECh. 7 - Estimate the osmotic pressure, freezing point, and...Ch. 7 - In February 2006, a pharmacy technician...Ch. 7 - Prob. 7.74ECh. 7 - Calculate the freezing point depression of mercury...Ch. 7 - Glacial acetic acid has a melting point of 16.0C...Ch. 7 - Prob. 7.77ECh. 7 - Prob. 7.78ECh. 7 - Use the system in exercise 7.62 to calculate the...Ch. 7 - Prob. 7.80ECh. 7 - Prob. 7.81ECh. 7 - Prob. 7.82ECh. 7 - Prob. 7.83ECh. 7 - Prob. 7.84ECh. 7 - Prob. 7.85ECh. 7 - Determine osmotic pressures for each solution...Ch. 7 - Prob. 7.87ECh. 7 - The vapor pressures of benzene and and 1,1...Ch. 7 - Prob. 7.89ECh. 7 - Tabulate the solubility of naphthalene in toluene...
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- All structural types of Boron hydrides exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forwardN-nitrosodimethylamine (NDMA) is a suspected carcinogen that can form via reactions between dimethylamine (DMA) and monochloramine (NH2Cl). The relevant elementary reactions and the corresponding rate constants are as shown below. Reaction Rate constant (M¹s¹) DMA + NH2Cl = DMCA + NH3 k =1.4×10-1, kr = 5.83×10-3 1.28×10-3 DMA + NH2Cl → UDMH UDMH + NH2Cl → NDMA -> 1.11×10-1 If the initial concentrations of DMA and NH2Cl are given, you should be able to predict the concentrations of all species at any given reaction time. Please write down the rate equations for DMA, NH2C1, DMCA, UDMH and NDMA.arrow_forwardYou wish to add enough NaOCl (sodium hypochlorite) to a 150 m³ swimming pool to provide a dose of 5.0 mg/L TOTOCI as Cl2. (a) How much NaOCI (kg) should you add? (Note: the equivalent weight of NaOCl is based on the reaction: NaOCl + 2H + 2 e→CI + Na +H₂O.) (10 pts) (atomic weight: Na 23, O 16, C1 35.5) (b) The pH in the pool after the NaOCl addition is 8.67. To improve disinfection, you want at least 90% of the TOTOCI to be in the form of HOCI (pKa 7.53). Assuming that HOCI/OCI is the only weak acid/base group in solution, what volume (L) of 10 N HCl must be added to achieve the goal? (15 pts) Note that part a) is a bonus question for undergraduate students. If you decide not to work on this part of the question, you many assume TOTOCI = 7×10-5 M for part b).arrow_forward
- Part A 2K(s)+Cl2(g)+2KCI(s) Express your answer in grams to three significant figures. Part B 2K(s)+Br2(1)→2KBr(s) Express your answer in grams to three significant figures. Part C 4Cr(s)+302(g)+2Cr2O3(s) Express your answer in grams to three significant figures. Part D 2Sr(s)+O2(g) 2SrO(s) Express your answer in grams to three significant figures. Thank you!arrow_forwardA solution contains 10-28 M TOTCO3 and is at pH 8.1. How much HCI (moles per liter of solution) is required to titrate the solution to pH 7.0? (H2CO3: pKa1=6.35, pKa2=10.33)arrow_forwardDon't used Ai solutionarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY