CHEMISTRY 1111 LAB MANUAL >C<
1st Edition
ISBN: 9781307092097
Author: Chang
Publisher: MCG/CREATE
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Textbook Question
Chapter 7, Problem 7.70QP
Which orbital in each of the following pairs is lower in energy in a many-electron atom? (a) 2s, 2p; (b) 3p, 3d; (c) 3s, 4s; (d) 4d, 5f.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
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30
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10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 7 Solutions
CHEMISTRY 1111 LAB MANUAL >C<
Ch. 7.1 - Which of the waves (a)(c) has (i) the highest...Ch. 7.1 - What is the wavelength (in meters) of an...Ch. 7.1 - Why is radiation only in the UV but not the...Ch. 7.2 - The energy of a photon is 5.87 1020 J. What is...Ch. 7.2 - The work function of titanium metal is 6.93 1019...Ch. 7.2 - A clean metal surface is irradiated with light of...Ch. 7.3 - What is the wavelength (in nanometers) of a photon...Ch. 7.3 - Which transition in the hydrogen atom would emit...Ch. 7.4 - Calculate the wavelength (in nanometers) of a H...Ch. 7.4 - Which quantity in Equation (7.8) is responsible...
Ch. 7.5 - Estimate the uncertainty in the speed of an oxygen...Ch. 7.5 - What is the difference between and 2 for the...Ch. 7.6 - Give the four quantum numbers for each of the two...Ch. 7.7 - Give the values of the quantum numbers associated...Ch. 7.7 - What is the total number of orbitals associated...Ch. 7.7 - Why is it not possible to have a 2d orbital, but a...Ch. 7.8 - Write the four quantum numbers for an electron in...Ch. 7.8 - Prob. 10PECh. 7.8 - Write a complete set of quantum numbers for each...Ch. 7.8 - The ground-state electron configuration of an atom...Ch. 7.9 - Prob. 12PECh. 7.9 - Identify the element that has the following...Ch. 7 - What is a wave? Explain the following terms...Ch. 7 - What are the units for wavelength and frequency of...Ch. 7 - List the types of electromagnetic radiation,...Ch. 7 - Give the high and low wavelength values that...Ch. 7 - Briefly explain Plancks quantum theory and explain...Ch. 7 - Prob. 7.6QPCh. 7 - (a) What is the wavelength (in nm) of light having...Ch. 7 - (a) What is the frequency of light having a...Ch. 7 - Prob. 7.9QPCh. 7 - How many minutes would it take a radio wave to...Ch. 7 - The SI unit of time is the second, which is...Ch. 7 - Prob. 7.12QPCh. 7 - What are photons? What role did Einsteins...Ch. 7 - Consider the plots shown here for the...Ch. 7 - A photon has a wavelength of 624 nm. Calculate the...Ch. 7 - The blue color of the sky results from the...Ch. 7 - A photon has a frequency of 6.0 104 Hz. (a)...Ch. 7 - What is the wavelength, in nm, of radiation that...Ch. 7 - When copper is bombarded with high-energy...Ch. 7 - A particular form of electromagnetic radiation has...Ch. 7 - The work function of potassium is 3.68 1019 J....Ch. 7 - When light of frequency equal to 2.11 1015 s1...Ch. 7 - (a) What is an energy level? Explain the...Ch. 7 - Prob. 7.24QPCh. 7 - Explain why elements produce their own...Ch. 7 - Prob. 7.26QPCh. 7 - Prob. 7.27QPCh. 7 - Explain how astronomers are able to tell which...Ch. 7 - Consider the following energy levels of a...Ch. 7 - Prob. 7.30QPCh. 7 - Calculate the wavelength (in nm) of a photon...Ch. 7 - Calculate the frequency (Hz) and wavelength (nm)...Ch. 7 - Prob. 7.33QPCh. 7 - An electron in the hydrogen atom makes a...Ch. 7 - Explain the statement, Matter and radiation have a...Ch. 7 - How does de Broglies hypothesis account for the...Ch. 7 - Why is Equation (7.8) meaningful only for...Ch. 7 - (a) If a H atom and a He atom are traveling at the...Ch. 7 - Prob. 7.39QPCh. 7 - Protons can be accelerated to speeds near that of...Ch. 7 - What is the de Broglie wavelength, in centimeters,...Ch. 7 - What is the de Broglie wavelength (in nm)...Ch. 7 - What are the inadequacies of Bohrs theory?Ch. 7 - What is the Heisenberg uncertainty principle? What...Ch. 7 - Prob. 7.45QPCh. 7 - How is the concept of electron density used to...Ch. 7 - What is an atomic orbital? How does an atomic...Ch. 7 - Describe the shapes of s, p, and d orbitals. How...Ch. 7 - List the hydrogen orbitals in increasing order of...Ch. 7 - Prob. 7.50QPCh. 7 - Why is a boundary surface diagram useful in...Ch. 7 - Prob. 7.52QPCh. 7 - Which quantum number defines a shell? Which...Ch. 7 - Which of the four quantum numbers (n, , m, ms)...Ch. 7 - Prob. 7.55QPCh. 7 - An electron in an atom is in the n = 3 quantum...Ch. 7 - Give the values of the quantum numbers associated...Ch. 7 - Give the values of the four quantum numbers of an...Ch. 7 - Prob. 7.59QPCh. 7 - What is the difference between a 2px and a 2py...Ch. 7 - Prob. 7.61QPCh. 7 - List all the possible subshells and orbitals...Ch. 7 - Calculate the total number of electrons that can...Ch. 7 - Prob. 7.64QPCh. 7 - Prob. 7.65QPCh. 7 - Indicate the total number of (a) p electrons in N...Ch. 7 - Make a chart of all allowable orbitals in the...Ch. 7 - Why do the 3s, 3p, and 3d orbitals have the same...Ch. 7 - For each of the following pairs of hydrogen...Ch. 7 - Which orbital in each of the following pairs is...Ch. 7 - What is electron configuration? Describe the roles...Ch. 7 - Prob. 7.72QPCh. 7 - Prob. 7.73QPCh. 7 - What is meant by the term shielding of electrons...Ch. 7 - Indicate which of the following sets of quantum...Ch. 7 - The ground-state electron configurations listed...Ch. 7 - The atomic number of an element is 73. Is this...Ch. 7 - Indicate the number of unpaired electrons present...Ch. 7 - State the Aufbau principle and explain the role it...Ch. 7 - Prob. 7.80QPCh. 7 - What is the noble gas core? How does it simplify...Ch. 7 - What are the group and period of the element...Ch. 7 - Prob. 7.83QPCh. 7 - Explain why the ground-state electron...Ch. 7 - Prob. 7.85QPCh. 7 - Comment on the correctness of the following...Ch. 7 - Prob. 7.87QPCh. 7 - Use the Aufbau principle to obtain the...Ch. 7 - Prob. 7.89QPCh. 7 - Prob. 7.90QPCh. 7 - The electron configuration of a neutral atom is...Ch. 7 - Which of the following species has the most...Ch. 7 - A sample tube consisted of atomic hydrogens in...Ch. 7 - A laser produces a beam of light with a wavelength...Ch. 7 - When a compound containing cesium ion is heated in...Ch. 7 - Prob. 7.96QPCh. 7 - Prob. 7.97QPCh. 7 - Prob. 7.98QPCh. 7 - Identify the following individuals and their...Ch. 7 - What properties of electrons are used in the...Ch. 7 - A certain pitchers fastballs have been clocked at...Ch. 7 - A student carried out a photoelectric experiment...Ch. 7 - (a) What is the lowest possible value of the...Ch. 7 - Considering only the ground-state electron...Ch. 7 - A ruby laser produces radiation of wavelength 633...Ch. 7 - A 368-g sample of water absorbs infrared radiation...Ch. 7 - Photodissociation of water H2O(l)+hvH2(g)+12O2(g)...Ch. 7 - Prob. 7.109QPCh. 7 - An atom moving at its root-mean-square speed at...Ch. 7 - Prob. 7.111QPCh. 7 - The He+ ion contains only one electron and is...Ch. 7 - Ozone (O3) in the stratosphere absorbs the harmful...Ch. 7 - The retina of a human eye can detect light when...Ch. 7 - A helium atom and a xenon atom have the same...Ch. 7 - Prob. 7.116QPCh. 7 - Prob. 7.117QPCh. 7 - A photoelectric experiment was performed by...Ch. 7 - Draw the shapes (boundary surfaces) of the...Ch. 7 - The electron configurations described in this...Ch. 7 - Draw orbital diagrams for atoms with the following...Ch. 7 - Prob. 7.122QPCh. 7 - Scientists have found interstellar hydrogen atoms...Ch. 7 - Prob. 7.124QPCh. 7 - Ionization energy is the minimum energy required...Ch. 7 - An electron in a hydrogen atom is excited from the...Ch. 7 - Prob. 7.127QPCh. 7 - Prob. 7.128QPCh. 7 - Prob. 7.129QPCh. 7 - Shown are portions of orbital diagrams...Ch. 7 - The UV light that is responsible for tanning the...Ch. 7 - The sun is surrounded by a white circle of gaseous...Ch. 7 - Prob. 7.133QPCh. 7 - Prob. 7.134QPCh. 7 - Prob. 7.135QPCh. 7 - In an electron microscope, electrons are...Ch. 7 - Prob. 7.137QPCh. 7 - The radioactive Co-60 isotope is used in nuclear...Ch. 7 - (a) An electron in the ground state of the...Ch. 7 - One wavelength in the hydrogen emission spectrum...Ch. 7 - Owls have good night vision because their eyes can...Ch. 7 - For hydrogenlike ions, that is, ions containing...Ch. 7 - When two atoms collide, some of their kinetic...Ch. 7 - Calculate the energies needed to remove an...Ch. 7 - The de Broglie wavelength of an accelerating...Ch. 7 - The minimum uncertainty in the position of a...Ch. 7 - According to Einsteins special theory of...Ch. 7 - The mathematical equation for studying the...Ch. 7 - In the beginning of the twentieth century, some...Ch. 7 - Blackbody radiation is the term used to describe...Ch. 7 - Prob. 7.151QPCh. 7 - The wave function for the 2s orbital in the...Ch. 7 - A student placed a large unwrapped chocolate bar...Ch. 7 - The wave properties of matter can generally be...Ch. 7 - Atoms of an element have only two accessible...Ch. 7 - Prob. 7.156IMECh. 7 - Only a fraction of the electrical energy supplied...Ch. 7 - Prob. 7.158IMECh. 7 - A typical red laser pointer has a power of 5 mW....Ch. 7 - Referring to the Chemistry in Action essay Quantum...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
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