Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
7th Edition
ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 7, Problem 7.60CP
Interpretation Introduction
To determine:
The name of each of the following molecular compounds :
PCl3,N2O3,P4O7,BrF3,NCl3,P4O6,S2F2,SeO2
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 7 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 7 - Prob. 7.1PCh. 7 - Conceptual APPLY 7.2 An electrostatic potential...Ch. 7 - Prob. 7.3PCh. 7 - Prob. 7.4ACh. 7 - Prob. 7.5PCh. 7 - Prob. 7.6ACh. 7 - Prob. 7.7PCh. 7 - Prob. 7.8ACh. 7 - Prob. 7.9PCh. 7 - Prob. 7.10A
Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12ACh. 7 - Prob. 7.13PCh. 7 - Prob. 7.14ACh. 7 - Prob. 7.15PCh. 7 - Prob. 7.16ACh. 7 - Prob. 7.17PCh. 7 - Prob. 7.18ACh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20ACh. 7 - Prob. 7.21PCh. 7 - Prob. 7.22ACh. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Prob. 7.27PCh. 7 - Prob. 7.28PCh. 7 - Prob. 7.29CPCh. 7 - Prob. 7.30CPCh. 7 - Prob. 7.31CPCh. 7 - Prob. 7.32CPCh. 7 - Prob. 7.33CPCh. 7 - Prob. 7.34CPCh. 7 - Prob. 7.35CPCh. 7 - Prob. 7.36CPCh. 7 - Prob. 7.37CPCh. 7 - Prob. 7.38CPCh. 7 - Prob. 7.39CPCh. 7 - Prob. 7.40CPCh. 7 - Prob. 7.41CPCh. 7 - Prob. 7.42CPCh. 7 - Prob. 7.43CPCh. 7 - Prob. 7.44CPCh. 7 - Prob. 7.45CPCh. 7 - Prob. 7.46CPCh. 7 - Prob. 7.47CPCh. 7 - Prob. 7.48CPCh. 7 - Which of the substances...Ch. 7 - Prob. 7.50CPCh. 7 - Order the following compounds according to the...Ch. 7 - Prob. 7.52CPCh. 7 - Prob. 7.53CPCh. 7 - Prob. 7.54CPCh. 7 - Prob. 7.55CPCh. 7 - Explain the difference in the bond dissociation...Ch. 7 - Explain the difference in the bond dissociation...Ch. 7 - Prob. 7.58CPCh. 7 - Prob. 7.59CPCh. 7 - Prob. 7.60CPCh. 7 - Prob. 7.61CPCh. 7 - Prob. 7.62CPCh. 7 - Prob. 7.63CPCh. 7 - Prob. 7.64CPCh. 7 - Prob. 7.65CPCh. 7 - Prob. 7.66CPCh. 7 - Prob. 7.67CPCh. 7 - Prob. 7.68CPCh. 7 - Prob. 7.69CPCh. 7 - Prob. 7.70CPCh. 7 - Prob. 7.71CPCh. 7 - Identify the third-row elements, X, that form the...Ch. 7 - Identify the fourth-row elements, X, that form the...Ch. 7 - Prob. 7.74CPCh. 7 - Prob. 7.75CPCh. 7 - Methyiphenidat (C14H19NO2) , marketed as Ritalin,...Ch. 7 - Prob. 7.77CPCh. 7 - Prob. 7.78CPCh. 7 - Prob. 7.79CPCh. 7 - Prob. 7.80CPCh. 7 - Prob. 7.81CPCh. 7 - Prob. 7.82CPCh. 7 - Prob. 7.83CPCh. 7 - Prob. 7.84CPCh. 7 - Prob. 7.85CPCh. 7 - Prob. 7.86CPCh. 7 - Prob. 7.87CPCh. 7 - Prob. 7.88CPCh. 7 - Prob. 7.89CPCh. 7 - Prob. 7.90CPCh. 7 - Draw two electron-dot resonance structures that...Ch. 7 - Prob. 7.92CPCh. 7 - Prob. 7.93CPCh. 7 - Prob. 7.94CPCh. 7 - Prob. 7.95CPCh. 7 - Prob. 7.96CPCh. 7 - Prob. 7.97CPCh. 7 - Prob. 7.98CPCh. 7 - Prob. 7.99CPCh. 7 - Write an electron-dot structure for chloral...Ch. 7 - Prob. 7.101CPCh. 7 - Prob. 7.102CPCh. 7 - Prob. 7.103CPCh. 7 - Prob. 7.104CPCh. 7 - Prob. 7.105CPCh. 7 - 7.106 Themolecule has nitrogen-oxygen bonds, but...Ch. 7 - Prob. 7.107CPCh. 7 - Prob. 7.108MPCh. 7 - Prob. 7.109MPCh. 7 - Prob. 7.110MPCh. 7 - Prob. 7.111MPCh. 7 - Prob. 7.112MP
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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