Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 7, Problem 75E
Write complete ionic and net ionic equations for each of the reactions in problem 67.
Write a molecular equation for the precipitation reaction that occurs (if any) when each pair of solutions is mixed. If no reaction occurs, write NO REACTION.
a. sodium carbonate and lead (II) nitrate
b. potassium sulfate and lead (II) acetate
c. copper (II) nitrate and barium sulfide
d. calcium nitrate and sodium iodide
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
Chapter 7 Solutions
Introductory Chemistry (6th Edition)
Ch. 7 - Which process is a chemical reaction? a. Gasoline...Ch. 7 - How many oxygen atoms are on the reactant side of...Ch. 7 - Q3. What is the coefficient for hydrogen in the...Ch. 7 - Q4. Determine the correct set of coefficients to...Ch. 7 - Which compound is soluble in water? a. Fe(OH)2 b....Ch. 7 - Name the precipitate that forms (if any) when...Ch. 7 - Q7. Which set of reactants forms a solid...Ch. 7 - Q8. What is the net ionic equation for the...Ch. 7 - Q9. Complete the equation:
a.
b.
c.
d. No...Ch. 7 - Prob. 10SAQ
Ch. 7 - What are the products of the balanced equation for...Ch. 7 - Q12. Precipitation reactions are best classified...Ch. 7 - 1. What is a chemical reaction? List some...Ch. 7 - If you could observe atoms and molecules with the...Ch. 7 - 3. What are the main indications that a chemical...Ch. 7 - What is a chemical equation? Provide an example...Ch. 7 - Prob. 5ECh. 7 - To balance a chemical equation, adjust the...Ch. 7 - 7. Is the chemical equation balanced? Why or why...Ch. 7 - 8. What is an aqueous solution? List two...Ch. 7 - 9. What does it mean if a compound is referred to...Ch. 7 - Explain what happens to an ionic substance when it...Ch. 7 - Do polyatomic ions dissociate when they dissolve...Ch. 7 - What is a strong electrolyte solution?Ch. 7 - 13. What are the solubility rules, and how are...Ch. 7 - What is a precipitation reaction? Provide an...Ch. 7 - 15. Is the precipitate in a precipitation reaction...Ch. 7 - 16. Describe the difference between a molecular...Ch. 7 - What is an acid-base reaction? List an example and...Ch. 7 - Prob. 18ECh. 7 - What is a gas evolution reaction? Give an example.Ch. 7 - What is a redox reaction? Give an example.Ch. 7 - Prob. 21ECh. 7 - Prob. 22ECh. 7 - 23. Explain the difference between a synthesis...Ch. 7 - 24. Explain the difference between a...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Vinegar forms bubbles when it is poured into the...Ch. 7 - When a chemical drain opener is added to a clogged...Ch. 7 - 29. When a commercial hair bleaching mixture is...Ch. 7 - When water is boiled in a pot, it bubbles. Has a...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - 33. Consider the unbalanced chemical equation.
A...Ch. 7 - Consider the unbalanced chemical equation....Ch. 7 - Prob. 35ECh. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - 39. When solid sodium is added to liquid water, it...Ch. 7 - When iron rusts, solid iron reacts with gaseous...Ch. 7 - 41. Sulfuric acid in acid rain forms when gaseous...Ch. 7 - Nitric acid in acid rain forms when gaseous...Ch. 7 - Prob. 43ECh. 7 - Prob. 44ECh. 7 - 45. Write a balance chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 47. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 49. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 51. Is each chemical equation correctly balanced?...Ch. 7 - Prob. 52ECh. 7 - Prob. 53ECh. 7 - Propane camping stoves produce heat by the...Ch. 7 - 55. Catalytic converters work to remove nitrogen...Ch. 7 - Prob. 56ECh. 7 - 57. Is each compound soluble or insoluble? For the...Ch. 7 - 58. Is each compound soluble or insoluble? For the...Ch. 7 - 59. Pair each cation on the left with an anion on...Ch. 7 - Pair each cation on the left with an anion on the...Ch. 7 - 61. Move any misplaced compounds to the correct...Ch. 7 - Prob. 62ECh. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Correct any incorrect equations. If no reaction...Ch. 7 - 68. Correct any incorrect equations. If no...Ch. 7 - 69. Identify the spectator ions in the complete...Ch. 7 - Identify the spectator ions in the complete ionic...Ch. 7 - 71. Write balanced complete ionic and net ionic...Ch. 7 - Write balanced complete ionic and net ionic...Ch. 7 - Mercury(I) ions (Hg22+) can be removed from...Ch. 7 - 74. Lead ions can be removed from solution by...Ch. 7 - Write complete ionic and net ionic equations for...Ch. 7 - 76. Write complete ionic and net ionic equations...Ch. 7 - When a hydrochloric acid solution is combined with...Ch. 7 - 78. A breaker of nitric acid is neutralized with...Ch. 7 - 79. Complete and balance each acid-base...Ch. 7 - Complete and balance each acid-base reaction. a....Ch. 7 - 81. Complete and balance each gas evolution...Ch. 7 - Complete and balance each gas evolution reaction....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Prob. 85ECh. 7 - 86. Complete and balance each combustion...Ch. 7 - 87. Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 89. Classify each chemical reaction as a...Ch. 7 - 90. Classify each chemical reaction as a...Ch. 7 - Prob. 91ECh. 7 - 92. A main source of soulful oxide pollutants are...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Prob. 95ECh. 7 - 96. Predict the products of each reaction and...Ch. 7 - Predict the type of reaction (if any) that occurs...Ch. 7 - Prob. 98ECh. 7 - Classify each reaction in as many ways as...Ch. 7 - Classify each reaction in as many ways as...Ch. 7 - Hard water often contains dissolved Ca2+ and Mg2+...Ch. 7 - Lakes that have been acidified by acid rain...Ch. 7 - 103. What solution can you add to each cation...Ch. 7 - Prob. 104ECh. 7 - A solution contains an unknown amount of dissolved...Ch. 7 - Prob. 106ECh. 7 - Prob. 107ECh. 7 - Prob. 108ECh. 7 - 109. Shown here are molecular views of two...Ch. 7 - Precipitation reactions often produce brilliant...Ch. 7 - Prob. 111QGWCh. 7 - Memorize the solubility rules. Without referring...Ch. 7 - Define and give an example of each of the...Ch. 7 - Water samples often contain dissolved ions such as...
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