EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
Question
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Chapter 7, Problem 7.52SP

(a)

Interpretation Introduction

To determine: The major product of acid-catalyzed dehydration of the given alcohol, pentan2ol.

Interpretation: The major product of acid-catalyzed dehydration of the given alcohol, pentan2ol is to be predicted.

Concept introduction: The chemical reaction that consists of an alkyl halide, a good leaving group that reacts with Lewis base to form an alkene is termed as elimination reaction. In this reaction there is complete removal of the leaving group without any substitution.

In acid-catalyzed dehydration, a saturated compound is converted to an unsaturated compound in the presence of an acid catalyst.

(b)

Interpretation Introduction

To determine: The major product of acid-catalyzed dehydration of the given alcohol, 1methylcyclopentanol.

Interpretation: The major product of acid-catalyzed dehydration of the given alcohol, 1methylcyclopentanol is to be predicted.

Concept introduction: The chemical reaction that consists of an alkyl halide, a good leaving group that reacts with Lewis base to form an alkene is termed as elimination reaction. In this reaction there is complete removal of the leaving group without any substitution.

In acid-catalyzed dehydration, a saturated compound is converted to an unsaturated compound in the presence of an acid catalyst.

(c)

Interpretation Introduction

To determine: The major product of acid-catalyzed dehydration of the given alcohol, 2methylcyclohexanol.

Interpretation: The major product of acid-catalyzed dehydration of the given alcohol, 2methylcyclohexanol is to be predicted.

Concept introduction: The chemical reaction that consists of an alkyl halide, a good leaving group that reacts with Lewis base to form an alkene is termed as elimination reaction. In this reaction there is complete removal of the leaving group without any substitution.

In acid-catalyzed dehydration, a saturated compound is converted to an unsaturated compound in the presence of an acid catalyst.

(d)

Interpretation Introduction

To determine: The major product of acid-catalyzed dehydration of the given alcohol, 2,2dimethylpropan-1-ol.

Interpretation: The major product of acid-catalyzed dehydration of the given alcohol, 2,2dimethylpropan-1-ol is to be predicted.

Concept introduction: The chemical reaction that consists of an alkyl halide, a good leaving group that reacts with Lewis base to form an alkene is termed as elimination reaction. In this reaction there is complete removal of the leaving group without any substitution.

In acid-catalyzed dehydration, a saturated compound is converted to an unsaturated compound in the presence of an acid catalyst.

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Chapter 7 Solutions

EP ORGANIC CHEMISTRY -MOD.MASTERING 18W

Ch. 7.8B - Use the data in Table7-2 to predict the energy...Ch. 7.8C - Prob. 7.13PCh. 7.8E - Explain why each of the following alkenes is...Ch. 7.8F - Prob. 7.15PCh. 7.10 - Prob. 7.16PCh. 7.10A - SN1 substitution and E1 elimination frequently...Ch. 7.10C - Prob. 7.18PCh. 7.10C - Prob. 7.19PCh. 7.10C - Prob. 7.20PCh. 7.11 - Prob. 7.21PCh. 7.11 - Prob. 7.22PCh. 7.12 - Prob. 7.23PCh. 7.12 - Prob. 7.24PCh. 7.13 - Prob. 7.25PCh. 7.14B - Prob. 7.26PCh. 7.14B - Make models of the blowing compounds, and predict...Ch. 7.15 - Prob. 7.28PCh. 7.15 - Prob. 7.29PCh. 7.15 - Prob. 7.30PCh. 7.15 - Prob. 7.31PCh. 7.16 - Predict the major and minor elimination products...Ch. 7.17B - Predict the products and mechanisms of the...Ch. 7.18 - Propose mechanisms for the following reactions.Ch. 7.18 - Prob. 7.35PCh. 7.19B - The dehydrogenation of butane to trans-but-2-ene...Ch. 7.19B - Prob. 7.37PCh. 7.19B - Prob. 7.38PCh. 7.19B - Prob. 7.39PCh. 7 - Prob. 7.40SPCh. 7 - Prob. 7.41SPCh. 7 - Prob. 7.42SPCh. 7 - Prob. 7.43SPCh. 7 - Prob. 7.44SPCh. 7 - Prob. 7.45SPCh. 7 - Prob. 7.46SPCh. 7 - The energy difference between cis- and...Ch. 7 - Prob. 7.48SPCh. 7 - Prob. 7.49SPCh. 7 - Prob. 7.50SPCh. 7 - What halides would undergo E2 dehydrohalogenation...Ch. 7 - Prob. 7.52SPCh. 7 - Prob. 7.53SPCh. 7 - Write a balanced equation for each reaction,...Ch. 7 - Prob. 7.55SPCh. 7 - Using cyclohexane as your starting material, show...Ch. 7 - Show how you would prepare cyclopentene from each...Ch. 7 - Prob. 7.58SPCh. 7 - E1 eliminations of alkyl halides are rarely useful...Ch. 7 - Prob. 7.60SPCh. 7 - Propose mechanisms for the following reactions....Ch. 7 - Prob. 7.62SPCh. 7 - Prob. 7.63SPCh. 7 - Prob. 7.64SPCh. 7 - Prob. 7.65SPCh. 7 - Prob. 7.66SPCh. 7 - Prob. 7.67SPCh. 7 - Prob. 7.68SPCh. 7 - Prob. 7.69SPCh. 7 - Explain the dramatic difference in rotational...Ch. 7 - One of the following dichloronorbornanes undergoes...Ch. 7 - A graduate student wanted to make...Ch. 7 - Prob. 7.73SPCh. 7 - Prob. 7.74SPCh. 7 - Prob. 7.75SPCh. 7 - Prob. 7.76SP
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