Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 7, Problem 72E
The combustion of liquid ethanol (C2H5OH) produces carbon dioxide and water. After 4.62 mL of ethanol (density = 0.789 g/mL) burns in the presence of 15.55 g of oxygen gas, 3.72 mL of water (density = 1.00 g/mL) is collected. Determine the limiting reactant, theoretical yield of H2O, and percent yield for the reaction. (Hint.Write a balanced equation for the combustion of ethanol.)
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My Organic Chemistry textbook says about the formation of cyclic hemiacetals, "Such intramolecular reactions to form five- and six-membered rings are faster than the corresponding intermolecular reactions. The two reacting functional groups, in this case OH and C=O, are held in close proximity, increasing the probability of reaction."According to the book, the formation of cyclic hemiacetals occurs in acidic conditions. So my question is whether the carbonyl group in this reaction reacts first with the end alcohol on the same molecule or with the ethylene glycol. And, given the explanation in the book, if it reacts first with ethylene glycol before its own end alcohol, why would it? I don't need to know the final answer. I need to know WHY it would not undergo an intermolecular reaction prior to reacting with the ethylene glycol if that is the case. Please do not use an AI answer.
Don't used hand raiting and don't used Ai solution
Chapter 7 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 7 - Prob. 1ECh. 7 - Prob. 2ECh. 7 - What is the difference between a physical change...Ch. 7 - What is the difference between a physical property...Ch. 7 - What is a balanced chemical equation?Ch. 7 - Why must chemical equations be balanced?Ch. 7 - What is reaction stoichiometry? What is the...Ch. 7 - In a chemical reaction, what is the limiting...Ch. 7 - In a chemical reaction, what is the theoretical...Ch. 7 - We typically calculate the percent yield using the...
Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Write a general equation for the reaction of an...Ch. 7 - Prob. 14ECh. 7 - Classify each change as physical or chemical....Ch. 7 - Prob. 16ECh. 7 - Prob. 17ECh. 7 - Prob. 18ECh. 7 - Classify each of the listed properties of...Ch. 7 - Prob. 20ECh. 7 - Classify each property as physical or chemical the...Ch. 7 - Prob. 22ECh. 7 - Sulfuric acid (H2SO4) is a component of acid rain...Ch. 7 - Nitric acid (HNO3) is a component of acid rain...Ch. 7 - Prob. 25ECh. 7 - Prob. 26ECh. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced equation for the photosynthesis...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Balance each chemical equation. CO2(g) + CaSiO3(s)...Ch. 7 - Balance each chemical equation. Na2S(aq) +...Ch. 7 - Prob. 35ECh. 7 - Consider the unbalanced equation for the...Ch. 7 - Calculate how many moles of NO2 form when each...Ch. 7 - Calculate how many moles of NH3 form when each...Ch. 7 - Consider the balanced equation: SiO2(s) + 3 C(s)...Ch. 7 - Consider the balanced equation: 2 N2H4(s) +...Ch. 7 - Hydrobromic acid (HBr) dissolves solid iron...Ch. 7 - Sulfuric acid (H2SO4) dissolves aluminum metal...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For the following reaction, determine the limiting...Ch. 7 - Find the limiting reactant for each initial amount...Ch. 7 - Consider the reaction: HCl(g) + O2(g) 2 H2O(g) +...Ch. 7 - Consider the reaction: 2 CH 3 OH(g)+3 O 2 (g)2 CO...Ch. 7 - Calculate the theoretical yield of the product (in...Ch. 7 - Calculate the theoretical yield of product (in...Ch. 7 - Zinc sulfide reacts with oxygen according to the...Ch. 7 - Iron(ll) sulfide reacts with hydrochloric acid...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - Iron(lll) oxide reacts with carbon monoxide...Ch. 7 - Elemental phosphorus reacts with chlorine gas...Ch. 7 - Lead(ll) ions can be removed from solution with...Ch. 7 - Prob. 58ECh. 7 - Urea (CH4N2O) is a common fertilizer that is...Ch. 7 - Prob. 60ECh. 7 - Prob. 61ECh. 7 - Complete and balance each combustion reaction...Ch. 7 - Prob. 63ECh. 7 - Prob. 64ECh. 7 - Prob. 65ECh. 7 - Prob. 66ECh. 7 - Prob. 67ECh. 7 - Prob. 68ECh. 7 - Prob. 69ECh. 7 - Prob. 70ECh. 7 - Aspirin can be made in the laboratory by reacting...Ch. 7 - The combustion of liquid ethanol (C2H5OH) produces...Ch. 7 - Prob. 73ECh. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - An important reaction that takes place in a blast...Ch. 7 - A liquid fuel mixture contains 30.35% hexane...Ch. 7 - Titanium occurs in the magnetic mineral ilmenite...Ch. 7 - A mixture of C3H8 and C2H2 has a mass of 2.0 g. It...Ch. 7 - Prob. 80ECh. 7 - Lead poisoning is a serious condition resulting...Ch. 7 - Prob. 82ECh. 7 - Metallic aluminum reacts with MnO2 at elevated...Ch. 7 - Prob. 84ECh. 7 - Consider the reaction: 4K(s)+O2(g)2K2O(s) The...Ch. 7 - Prob. 86ECh. 7 - Consider the reaction:...Ch. 7 - Prob. 88ECh. 7 - Prob. 89ECh. 7 - Prob. 90ECh. 7 - What are the correct coefficients (reading from...Ch. 7 - Prob. 2SAQCh. 7 - Prob. 3SAQCh. 7 - For the reaction shown here, 3.5 mol A is mixed...Ch. 7 - Manganese(IV) oxide reacts with aluminum to form...Ch. 7 - Sodium and chlorine react to form sodium chloride....Ch. 7 - Sulfur and fluorine react to form sulfur...Ch. 7 - A reaction has a theoretical yield of 45.8 g. When...Ch. 7 - Prob. 9SAQCh. 7 - Solid potassium chlorate (KCIO3) decomposes into...
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