Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Question
Chapter 7, Problem 7.15P
Interpretation Introduction
Interpretation:
The methyl acetylene/allene mixture is prepared from propene using in the laboratory method has to be explained.
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Students have asked these similar questions
For small-scale and consumer welding applications, many hardware stores sell cylinders of MAAP gas, which is a mixture of propyne (methylacetylene) and 1,2-propadiene (allene), with other hydrocarbons. How would you prepare the methylacetylene/allene mixture from propene in the laboratory?
(5) One of Prof Cunningham's former students wrote his doctoral dissertation about a new
technology to clean up soil contaminated by certain types of chemicals. One of the
chemicals we tested in the lab was 1,2,4,5-tetrachlorobenzene (TECB).
(a) Draw the chemical structure of 1,2,4,5-tetrachlorobenzene.
(b) When we started working on the project, we thought maybe TeCB would be de-
stroyed according to first-order kinetics, but we weren't sure. Below are two tables
of actual data that the student collected in the laboratory. The two data sets were
collected under different experimental conditions. For each of the two experiments,
determine if the disappearance of TeCB is zero-order, first-order, second-order, or
something else. Specify the value of the rate constant (ko, k1, or k2, as appropriate).
Be sure to give the right units of k!
Table 1: Concentration of TECB vs. time, experiment 1
time (min)
Conc. (mg/L)
10
20
30
45
5.0
2.93
2.06
0.61
0.28
0.057
Table 2: Concentration of TECB…
Write the steps for formation of tetrachloromethane (CCl4) from the reaction of methane with Cl2 + hn.
Chapter 7 Solutions
Organic Chemistry
Ch. 7.2 - Write the IUPAC name of each compound.Ch. 7.2 - Write the common name of each alkyne.Ch. 7.5 - Prob. 7.3PCh. 7.7 - Draw a structural formula for a hydrocarbon with...Ch. 7.7 - Hydration of 2-pentyne gives a mixture of two...Ch. 7.9 - Prob. 7.6PCh. 7 - Prob. 7.7PCh. 7 - Show how to prepare each alkyne from the given...Ch. 7 - Prob. 7.9PCh. 7 - Complete each acid-base reaction and predict...
Ch. 7 - Draw structural formulas for the major product(s)...Ch. 7 - Draw the structural formula of the enol formed in...Ch. 7 - Prob. 7.13PCh. 7 - Prob. 7.14PCh. 7 - Prob. 7.15PCh. 7 - Show reagents and experimental conditions you...Ch. 7 - Show reagents and experimental conditions you...Ch. 7 - Show how to convert 1-butyne to each of these...Ch. 7 - Prob. 7.19PCh. 7 - Show reagents and experimental conditions to bring...Ch. 7 - Show reagents to bring about each conversion.Ch. 7 - Propose a synthesis for (Z)-9-tricosene...Ch. 7 - Propose a synthesis of each compound starting from...Ch. 7 - Show how to prepare each compound from 1-heptene....Ch. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Following is the structural formula of the...Ch. 7 - The standard procedure for synthesizing a compound...Ch. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Prob. 7.35P
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- Write the steps for formation of tetrachloromethane (CCl4) from the reaction of methane with Cl2 + hv.arrow_forward85. Propane, C3H8, is a hydrocarbon that is commonly used as a fuel. (a) Write a balanced equation for the complete combustion of propane gas. (b) Calculate the volume of air at 25 °C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint: We will see how to do this calculation in a later chapter on gases—for now use the information that 1.00 L of air at 25 °C and 1.00 atm contains 0.275 g of O2 per liter.) (c) The heat of combustion of propane is −2,219.2 kJ/mol. Calculate the heat of formation, ΔH∘fΔHf° of propane given that ΔH∘fΔHf° of H2O(l) = −285.8 kJ/mol and ΔH∘fΔHf° of CO2(g) = −393.5 kJ/mol. (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.arrow_forward3. Like polymers, dendrimers are macromolecules (large molecules). Some dendrimers have been used in applications like drug delivery and waste water reclamation. What is the result of the following reaction producing a "first generation" dendrimer? NH2 H2N. (-HCI) ???? 4 NH2arrow_forward
- 1) Compound 3-chlorobenzoic acid can be prepared from methylbenzene through a two- steps reaction. chemical equations for the reactions ? 2) 2 C12 (g) + 2 H20 (g) = 4 HCI (g) + 02 (g) Ac 2 HCI (g) + 1/2 02 (g) = C12 (g) + H20 (g) Ac' relationship between Ac and Ac' ? 3) Hydrogen iodide, HI decomposes 2HI (g) = H2 (g) + 12 (g) AH < 0 -2.00 atm of HI placed in a glass - allowed to reach equilibrium a) Ap for the reaction if 30.0% of HI decomposes ? b) the concentration of HI(g) will increase, decrease or remain the same when the temperature of reaction is increased ?arrow_forwardA student adds bromine solution to a test tube containing an isomer of C3H6. After shaking the sample and exposing it to UV light, the student observes that the colour of the bromine solution changes from orange to clear. Provide a hypothesis for what happened in the test tube. What do you believe to be the structure of the original isomer, and what was the final product, if a reaction occurred?arrow_forwardWrite a balanced equation to show the reaction of gaseous ethane with gaseous oxygen to form carbon monoxide gas and water vapor. C2H6(g)+7 O(g) → 2 CO2(g)+3 H2O(g)C2H6(g)+7 O(g) → 2 CO2(g)+3 H2O(g) C2H6(g)+5 O(g) → 2 CO(g)+3 H2O(g)C2H6(g)+5 O(g) → 2 CO(g)+3 H2O(g) 2 C2H6(g)+7 O2(g) → 4 CO2(g)+6 H2O(g)2 C2H6(g)+7 O2(g) → 4 CO2(g)+6 H2O(g) 2 C2H6(g)+5 O2(g) → 4 CO(g)+6 H2O(g)2 C2H6(g)+5 O2(g) → 4 CO(g)+6 H2O(g) 2 CH3(g)+5 O(g) → 2 CO(g)+3 H2O(g)2 CH3(g)+5 O(g) → 2 CO(g)+3 H2O(g)arrow_forward
- Consider the complete combustion of octane. Calculate the bond energies (in kJ/mol) for the:Combustion of methane CH4(g)+2O2(g)→CO2(g)+2H2O(g)a. bonds brokenb. bonds formedc. overall reactionarrow_forwardAcetylene is a very weak acid; however, it will react with moist silver(I) oxide and form water and a compound composed of silver and carbon. Addition of a solution of HCl to a 0.2352-g sample of the compound of silver andcarbon produced acetylene and 0.2822 g of AgCl.(a) What is the empirical formula of the compound of silver and carbon?(b) The production of acetylene on addition of HCl to the compound of silver and carbon suggests that the carbon is present as the acetylide ion, C22− . Write the formula of the compound showing the acetylide ion.arrow_forwardWrite the hydrohalogenation reaction of butene where the halogen is bromine.arrow_forward
- Propane, C3H8, is a hydrocarbon that is commonly used as a fuel.(a) Write a balanced equation for the complete combustion of propane gas.(b) Calculate the volume of air at 25 °C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint:use the information that 1.00 L of air at 25 °C and 1.00 atm contains 0.275 g of O2 per liter.)(c) The heat of combustion of propane is −2,219.2 kJ/mol. Calculate the heat of formation, ΔH°f of propane given that ΔH°f of H2O(l) = −285.8 kJ/mol and ΔH°f of CO2(g) = −393.5 kJ/mol. (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.arrow_forward21.) Calculate the enthalpy of hydrogenation of benzene to cyclohexane from the following reactions A,H (kJ/mol) C6H6 (1) + 15/2 02 (g) → 6 CO2 (g) + 3 H20 (1) C6H12 (1) + 9 02 (g) → 6 CO2 (g) + 6 H20 (1) H2 (g) + ½ 02 (g) → H2O (1) -3268 -3920 -285.83 a.) -205 kJ/mol b.) -1507 kJ/mol c.) -938 kJ/mol d.) -366 kJ/molarrow_forwardA student added bromine solution to a hydrocarbon sample that contained an isomer of C6H12 (E) in the absence of light. After shaking the sample, the student noticed that the colour of the bromine solution changed from orange to colourless. Use the following information to answer the question 6. An interpretation that could be made from the student's observations is that the hydrocarbon sample isi and the IUPAC name of the sample could be ii . The statement above is completed by the information in row: i saturated saturated unsaturated unsaturated Row A B C D wer (2 marks) ii hex-2-ene cyclopentane hex-2-ene cyclopentane 0arrow_forward
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