Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 7, Problem 7.15P
Interpretation Introduction

Interpretation:

The methyl acetylene/allene mixture is prepared from propene using in the laboratory method has to be explained.

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For small-scale and consumer welding applications, many hardware stores sell cylinders of MAAP gas, which is a mixture of propyne (methylacetylene) and 1,2-propadiene (allene), with other hydrocarbons. How would you prepare the methylacetylene/allene mixture from propene in the laboratory?
Write a balanced chemical equation for the reaction of ethene with oxygen. O a. C2H4(g) + 302(g) → 2CO2(g) + 2H2O(g) O b. 2C2H2(g) + 502(g) → 4CO2(g) + 2H2O(g) O c. CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) O d. C2H4(g) + 202(g) → 2CO2(g) + 2H2(g) O e. 2C2H6(g) + 702(g) →> 4CO2(g) + 6H2O(g)
(5) One of Prof Cunningham's former students wrote his doctoral dissertation about a new technology to clean up soil contaminated by certain types of chemicals. One of the chemicals we tested in the lab was 1,2,4,5-tetrachlorobenzene (TECB). (a) Draw the chemical structure of 1,2,4,5-tetrachlorobenzene. (b) When we started working on the project, we thought maybe TeCB would be de- stroyed according to first-order kinetics, but we weren't sure. Below are two tables of actual data that the student collected in the laboratory. The two data sets were collected under different experimental conditions. For each of the two experiments, determine if the disappearance of TeCB is zero-order, first-order, second-order, or something else. Specify the value of the rate constant (ko, k1, or k2, as appropriate). Be sure to give the right units of k! Table 1: Concentration of TECB vs. time, experiment 1 time (min) Conc. (mg/L) 10 20 30 45 5.0 2.93 2.06 0.61 0.28 0.057 Table 2: Concentration of TECB…

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Organic Chemistry

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