Molecular orbit ( M O T ) theory is more accurate theory than valence bond theory . In molecular orbital theory,we imagine that electronic orbitals cover the whole molecule and are not localised around one atom. Molecular orbital theory is based on wave superposition principle. Waves with same phase will interfere constructively and increase their amplitude. While opposite phases interfere destructively to decrease their amplitude. Concept introduction: From above it becomes clear that no of atomic orbital is equal to molecular orbital. No of atom in the given sample = mass of the given sample in gram ( molar mass ) N 11 a : 1 s 2 2 s 2 2 p 6 3 s 1 Each sodium atoms have one atomic orbital so no. of atomic orbital in the given sample of sodium is equal to the no. of atom, No. of molecular orbital in given sample is equal to no. of atomic orbital in given sample as from the above diagram molar mass of Na = 23 g / m o l e To determine: the no. of molecular orbitals present in the valence band of a sodium crystal with a mass of 5.45 g
Molecular orbit ( M O T ) theory is more accurate theory than valence bond theory . In molecular orbital theory,we imagine that electronic orbitals cover the whole molecule and are not localised around one atom. Molecular orbital theory is based on wave superposition principle. Waves with same phase will interfere constructively and increase their amplitude. While opposite phases interfere destructively to decrease their amplitude. Concept introduction: From above it becomes clear that no of atomic orbital is equal to molecular orbital. No of atom in the given sample = mass of the given sample in gram ( molar mass ) N 11 a : 1 s 2 2 s 2 2 p 6 3 s 1 Each sodium atoms have one atomic orbital so no. of atomic orbital in the given sample of sodium is equal to the no. of atom, No. of molecular orbital in given sample is equal to no. of atomic orbital in given sample as from the above diagram molar mass of Na = 23 g / m o l e To determine: the no. of molecular orbitals present in the valence band of a sodium crystal with a mass of 5.45 g
Solution Summary: The author explains that Molecular orbit theory is more accurate than valence bond theory. Waves with same phase will interfere constructively and increase their amplitude.
Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
Chapter 7, Problem 64E
Interpretation Introduction
Interpretation:
Molecular orbit theory is more accurate theory than valence bond theory. In molecular orbital theory,we imagine that electronic orbitals cover the whole molecule and are not localised around one atom. Molecular orbital theory is based on wave superposition principle. Waves with same phase will interfere constructively and increase their amplitude. While opposite phases interfere destructively to decrease their amplitude.
Concept introduction:
From above it becomes clear that no of atomic orbital is equal to molecular orbital.
No of atom in the given sample
Each sodium atoms have one atomic orbital so no. of atomic orbital in the given sample of sodium is equal to the no. of atom,
No. of molecular orbital in given sample is equal to no. of atomic orbital in given sample as from the above diagram
To determine: the no. of molecular orbitals present in the valence band of a sodium crystal with a mass of
Zeroth Order Reaction
In a certain experiment the decomposition of hydrogen iodide on finely divided gold is zeroth order with respect to HI.
2HI(g) Au H2(g) + 12(9)
Rate =
-d[HI]/dt k = 2.00x104 mol L-1 s-1
If the experiment has an initial HI concentration of 0.460 mol/L, what is the concentration of HI after 28.0 minutes?
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How long will it take for all of the HI to decompose?
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What is the rate of formation of H2 16.0 minutes after the reaction is initiated?
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Chapter 7 Solutions
Chemistry: Structure and Properties Plus MasteringChemistry with eText -- Access Card Package
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell