Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Chapter 7, Problem 45P
Interpretation Introduction
Interpretation:
How the rate of gaseous reaction can be increased without adding more reactants or catalyst and without changing temperature should be explained?
Concept Introduction:
Rate of gaseous reaction depends on many parameters like temperature, pressure, catalyst, addition of reactants and removal of products.
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Chapter 7 Solutions
Introduction to General, Organic and Biochemistry
Ch. 7.1 - Problem 7-1 In the reaction we measure the...Ch. 7.4 - Problem 7-2 Calculate the rate for the reaction in...Ch. 7.6 - Prob. 7.3QCCh. 7.6 - Prob. 7.4QCCh. 7.6 - Prob. 7.5QCCh. 7.7 - Prob. 7.6QCCh. 7.7 - Problem 7-7 Consider the following equilibrium...Ch. 7.7 - Prob. 7.8QCCh. 7.7 - Prob. 7.9QCCh. 7 - 7-11 Consider the following reaction: Suppose we...
Ch. 7 - 7-12 Two kinds of gas molecules are reacted at a...Ch. 7 - 7-13 Why are reactions between ions in aqueous...Ch. 7 - Prob. 4PCh. 7 - 7-15 A certain reaction is exothermic by 9...Ch. 7 - 7-16 A quart of milk quickly spoils if left at...Ch. 7 - 7-17 If a certain reaction takes 16 h to go to...Ch. 7 - Prob. 8PCh. 7 - Prob. 9PCh. 7 - Prob. 10PCh. 7 - Prob. 11PCh. 7 - 7-22 If you add a piece of marble, CaCO3 to a 6 M...Ch. 7 - Prob. 13PCh. 7 - Prob. 14PCh. 7 - Prob. 15PCh. 7 - 7-26 Write the chemical equations corresponding to...Ch. 7 - Prob. 17PCh. 7 - 7-28 When the following reaction reached...Ch. 7 - 7-29 The following reaction was allowed to reach...Ch. 7 - Prob. 20PCh. 7 - 7-31 Here are equilibrium constants for several...Ch. 7 - 7-32 A particular reaction has an equilibrium...Ch. 7 - Prob. 23PCh. 7 - Prob. 24PCh. 7 - 7-35 A reaction has a high rate constant but a...Ch. 7 - 7-36 Complete the following table showing the...Ch. 7 - Prob. 27PCh. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - 7-40 Is there any change in conditions that change...Ch. 7 - 7-41 The equilibrium constant at 1127°C for the...Ch. 7 - Prob. 32PCh. 7 - 7-43 (Chemical Connections 7A and 7B) Why is a...Ch. 7 - Prob. 34PCh. 7 - 7-45 (Chemical Connections 7C) A painkiller—for...Ch. 7 - 7-46 (Chemical Connections 7D) What reaction takes...Ch. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Prob. 39PCh. 7 - 7-50 Draw an energy diagram for an exothermic...Ch. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - 7-57 Write the reaction to which the following...Ch. 7 - Prob. 48PCh. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - 7-69 Pure carbon exists is several forms, two of...Ch. 7 - Prob. 60PCh. 7 - 7-71 You have a beaker that contains solid silver...Ch. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - Prob. 65PCh. 7 - Prob. 66PCh. 7 - Prob. 67PCh. 7 - Prob. 68PCh. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Prob. 71PCh. 7 - Prob. 72PCh. 7 - Prob. 73PCh. 7 - Prob. 74PCh. 7 - 7-82 An equilibrium mixture of O2, SO2, and SO3...Ch. 7 - Prob. 76PCh. 7 - Prob. 77P
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- The following equation represents a reversible decomposition: CaCO3(s)CaO(s)+CO2(g) Under what conditions will decomposition in a closed container proceed to completion so that no CaCO3 remains?arrow_forwardSubstances that poison a catalyst pose a major concern for many engineering designs, including those for catalytic converters. One design option is to add materials that react with potential poisons before they reach the catalyst. Among the commonly encountered catalyst poisons are silicon and phosphorus, which typically form phosphate or silicate ions in the oxidizing environment of an engine. Group 2 elements are added to the catalyst to react with these contaminants before they reach the working portion of the catalytic converter. If estimates show that a catalytic converter will be exposed to 625 g of silicon during its lifetime, what mass of beryllium would need to be included in the design?arrow_forward7-22 If you add a piece of marble, CaCO3 to a 6 M HCI solution at room temperature, you will see some bubbles form around the marble as gas slowly rises. If you crush another piece of marble and add it to the same solution at the same temperature, you will see vigorous gas formation, so much so that the solution appears to be boiling. Explain.arrow_forward
- Determine rxnH 25 C for the following reaction: NO g O2 g NO2 g This reaction is a major participant in the formation of smog.arrow_forwardSilicon forms a series of compounds analogous to the al-kanes and having the general formula SinH2n+2. The first of these compounds is silane, SiH4, which is used in the electronics industry to produce thin ultrapure silicon films. SiH4(g) is somewhat difficult to work with because it is py-ropboric at room temperature—meaning that it bursts into flame spontaneously when exposed to air. (a) Write an equation for the combustion of SiH4(g). (The reaction is analogous to hydrocarbon combustion, and SiO2 is a solid under standard conditions. Assume the water produced will be a gas.) (b) Use the data from Appendix E to calculate ? for this reaction. (c) Calculate G and show that the reaction is spontaneous at 25°C. (d) Compare G for this reaction to the combustion of methane. (See the previous problem.) Are the reactions in these two exercises enthalpy or entropy driven? Explain.arrow_forwardIn terms of collision theory, to which of the following is the rate of a chemical reaction proportional? (a) the change in free energy per second (b) the change in temperature per second (c) the number of collisions per second (d) the number of product moleculesarrow_forward
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