PRINCIPLES OF MODERN CHEMISTRY
PRINCIPLES OF MODERN CHEMISTRY
8th Edition
ISBN: 9780357671009
Author: OXTOBY
Publisher: CENGAGE L
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Chapter 7, Problem 43AP
Interpretation Introduction

Interpretation: The hydrocarbon that is oxidized to the butanoic acid and acetic acid in the presence of KMnO4 is to be determined.

Concept introduction:The hydrogenation is the type of the reaction in which unsaturated hydrocarbon is converted into the saturated hydrocarbon in the presence of the metal catalyst such as nickel and platinum.

The compound KMnO4 is the type of the strongest oxidizing agent.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…
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