(a) Interpretation: The ideal bond angles in NO 2 - need to be determined. Concept introduction: In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle. The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry. The geometry of a given can be predicted based on the general formula: AX n E m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Question

Which of the following would you expect to be antiaromatic? Please provide a detailed explanation.

Answer 1

Question

Chapter 7, Problem 38QAP

Interpretation Introduction

(a)

Interpretation:

The ideal bond angles in NO2- need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(b)

Interpretation:

The ideal bond angles in BF₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(c)

Interpretation:

The ideal bond angles in HNO₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(d)

Interpretation:

The ideal bond angles in CH₃ NH₂ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

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Which of the following would you expect to be antiaromatic? Please provide a detailed explanation.

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Answer 2

Question

Chapter 7, Problem 38QAP

Interpretation Introduction

(a)

Interpretation:

The ideal bond angles in NO2- need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(b)

Interpretation:

The ideal bond angles in BF₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(c)

Interpretation:

The ideal bond angles in HNO₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(d)

Interpretation:

The ideal bond angles in CH₃ NH₂ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

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Answer 3

Question

Chapter 7, Problem 38QAP

Interpretation Introduction

(a)

Interpretation:

The ideal bond angles in NO2- need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(b)

Interpretation:

The ideal bond angles in BF₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(c)

Interpretation:

The ideal bond angles in HNO₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(d)

Interpretation:

The ideal bond angles in CH₃ NH₂ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

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Answer 4

Question

Chapter 7, Problem 38QAP

Interpretation Introduction

(a)

Interpretation:

The ideal bond angles in NO2- need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(b)

Interpretation:

The ideal bond angles in BF₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(c)

Interpretation:

The ideal bond angles in HNO₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(d)

Interpretation:

The ideal bond angles in CH₃ NH₂ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

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Answer 5

Chapter 7, Problem 38QAP

Interpretation Introduction

(a)

Interpretation:

The ideal bond angles in NO2- need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(b)

Interpretation:

The ideal bond angles in BF₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(c)

Interpretation:

The ideal bond angles in HNO₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Interpretation Introduction

(d)

Interpretation:

The ideal bond angles in CH₃ NH₂ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 6

Chapter 7, Problem 38QAP

Interpretation Introduction

(a)

Interpretation:

The ideal bond angles in NO2- need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 7

Chapter 7, Problem 38QAP

Interpretation Introduction

(a)

Interpretation:

The ideal bond angles in NO2- need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ideal bond angles in BF₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ideal bond angles in BF₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 10

Interpretation Introduction

(c)

Interpretation:

The ideal bond angles in HNO₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 11

Interpretation Introduction

(c)

Interpretation:

The ideal bond angles in HNO₃ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 12

Interpretation Introduction

(d)

Interpretation:

The ideal bond angles in CH₃ NH₂ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 13

Interpretation Introduction

(d)

Interpretation:

The ideal bond angles in CH₃ NH₂ need to be determined.

Concept introduction:

In molecules with more than 2 atoms, the angle formed between 2 bonds is called as the bond angle.

The ideal geometry adopted by various molecules can be predicted based on the valence shell electron pair repulsion (VSEPR) theory. As per the VSEPR model, an orbital arrangement which minimizes valence electron repulsion leads to a stable geometry.

The geometry of a given can be predicted based on the general formula: AX_n E_m where A = central atom, X = surrounding atoms, E = lone pairs on the central atom

Answer 14

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Solution Summary: The author explains that the ideal bond angles in BF 3 need to be determined based on the valence shell electron pair repulsion theory.

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