EBK PRINCIPLES OF MODERN CHEMISTRY
EBK PRINCIPLES OF MODERN CHEMISTRY
8th Edition
ISBN: 9781305465091
Author: Butler
Publisher: YUZU
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Chapter 7, Problem 31P

(a)

Interpretation Introduction

Interpretation:

The structure formula of the carboxylic acid and the alcohol that are treated to form the methoprene is to be determined.

Concept Introduction:

The esterification is the type of the reaction in which the alcohol is treated with the carboxylic acid in order to form the ester.

(b)

Interpretation Introduction

Interpretation:

The name of the hydrocarbon that is formed by the replacement of OCH3 groups with the hydrogen atom and COOH group with the methyl group is to be determined.

Concept Introduction: The hydrocarbon is the type of the organic compound that is comprised of the carbon and the hydrogen atoms.

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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…
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