EBK CHEMISTRY: PRINCIPLES AND REACTIONS
8th Edition
ISBN: 9780100547964
Author: Hurley
Publisher: YUZU
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Chapter 7, Problem 23QAP
Interpretation Introduction
(a)
Interpretation:
Two other resonance structures for hydrazoic acid (N3 H) need to be drawn.
Concept introduction:
- A Lewis dot structure depicts bonding between atoms in a molecule in terms of the valence electrons, bonding electron pairs as well as the lone pairs surrounding individual atoms.
- If a molecule can be represented by more than one Lewis structure then the contributing forms which represent electron delocalization are termed as resonance structures.
Interpretation Introduction
(b)
Interpretation:
An explanation must be provided if the depicted structure of hydrazoic acid contributes to its resonance form.
Concept introduction:
- A Lewis dot structure depicts bonding between atoms in a molecule in terms of the valence electrons, bonding electron pairs as well as the lone pairs surrounding individual atoms.
- If a molecule can be represented by more than one Lewis structure then the contributing forms which represent electron delocalization are termed as resonance structures.
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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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Chapter 7 Solutions
EBK CHEMISTRY: PRINCIPLES AND REACTIONS
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