Concept explainers
(a)
Interpretation:
The pH of the
Concept Introduction :
The pH of the solution can be calculated using the following relation:
Here,
(b)
Interpretation:
The pH of the
Concept Introduction :
The pH of the solution can be calculated using the following relation:
Here,
(c)
Interpretation:
The pH of the
Concept Introduction :
The pH of the solution can be calculated using the following relation:
Here,
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Chemical Principles
- Consider a 0.67-M solution of C2H5NH2 (Kb = 5.6 104). a. Which of the following are major species in the solution? i. C2H5NH2 ii. H+ iii. OH iv. H2O v. C2H5NH3+ b. Calculate the pH of this solution.arrow_forwardConsider pyridine, C5H5N, a pesticide and deer repellent. Its conjugate acid, C5H5NH+, has K a =6.7106. (a) Write a balanced net ionic equation for the reaction that shows the basicity of aqueous solutions of pyridine. (b) Calculate Kb for the reaction in (a). (c) Find the pH of a solution prepared by mixing 2.74 g of pyridine in enough water to make 685 mL of solution.arrow_forwardThe pH of a 0.10-M solution of caffeine is 11.16. Determine Kb for caffeine from these data: C8H10N4O2(aq)+H2O(l)C8H10N4O2H+(aq)+OH(aq)arrow_forward
- The following illustration displays the relative number of species when an acid, HA, is added to water. a. Is HA a weak or strong acid? How can you tell? b. Using the relative numbers given in the illustration, determine the value for Ka and the percent dissociation of the acid. Assume the initial acid concentration is 0.20 M.arrow_forwardBarbituric acid, HC4H3N2O3, is used to prepare barbiturates, a class of drugs used as sedatives. A 325-mL aqueous solution of barbituric acid has a pH of 2.34 and contains 9.00 g of the acid. What is Ka for barbituric acid?arrow_forwardFind [OH+], [OH-] and the pH of the following solutions. (a) 30.0 mL of a 0.216 M solution of HCI diluted with enough water to make 125 mL of solution. (b) A solution made by dissolving 275 mL of HBr gas at 25C and 1.00 atm in enough water to make 475 mL of solution. Assume that all the HBr dissolves in water.arrow_forward
- Trimethylamine, (CH3)3N, is a gas with a fishy, ammonialike odor. An aqueous solution that is 0.25 M trimethylamine has a pH of 11.63. What is Kb for trimethylamine? Calculate the pH of a 0.35 M aqueous solution of trimethylamine.arrow_forwardAre solutions of the following salts acidic, basic, or neutral? For those that are not neutral, write balanced equations for the reactions causing the solution to be acidic or basic. The relevant Ka, and Kb values are found in Tables 13-2 and 13-3. a. Sr(NO3)2 b. NH4C2H3O2 c. CH3NH3Cl d. C6H5NH3ClO2 e. NH4F f. CH3NH3CNarrow_forwardWhat is the pH of a 0.10 M solution of oxalic acid, H2C2C4? What are the concentrations of H3O+, HC2O4, and the oxalate ion, C2O42? (See Appendix H for Ka values.)arrow_forward
- Codeine (Cod), a powerful and addictive painkiller, is a weak base. (a) Write a reaction to show its basic nature in water. Represent the codeine molecule as Cod. (b) The Ka for its conjugate acid is 1.2108. What is Kb for the reaction written in (a)? (c) What is the pH of a 0.0020 M solution of codeine?arrow_forwardNicotinic acid, C6H5NO2, is found in minute amounts in all living cells, hut appreciable amounts occur in liver, yeast, milk, adrenal glands, white meat, and corn. Whole wheat (lour contains about 60. 0g per gram of flour. One gram (1.00 g) of the acid dissolves in water to give 60. mL of solution having a pH of 2.70. What is the approximate value of Ka for the acid? Nicotinic acidarrow_forwardAcrylic acid (CH29CHCO2H) is a precursor for many important plastics. Ka for acrylic acid is 5.6 105. a. Calculate the pH of a 0.10-M solution of acrylic acid. b. Calculate the percent dissociation of a 0.10-M solution of acrylic acid. c. Calculate the pH of a 0.050-M solution of sodium acrylate (NaC3H3O2).arrow_forward
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