The sun supplies energy at a rate of about 1.0 kilowatt per square meter of surface area (1 watt = 1 J/s). The plants in an agricultural field produce the equivalent of 20. kg sucrose (C 12 H 22 O 1l ) per hour per hectare (1 ha = 10.000 m 2 ). Assuming that sucrose is produced by the reaction 12 CO 2 ( g ) + 11 H 2 O ( l ) → C 12 H 22 O 11 ( s ) + 12 O 2 ( g ) Δ H = 5640 KJ calculate the percentage of sunlight used to produce the sucrose—that is, determine the efficiency of photosynthesis.
The sun supplies energy at a rate of about 1.0 kilowatt per square meter of surface area (1 watt = 1 J/s). The plants in an agricultural field produce the equivalent of 20. kg sucrose (C 12 H 22 O 1l ) per hour per hectare (1 ha = 10.000 m 2 ). Assuming that sucrose is produced by the reaction 12 CO 2 ( g ) + 11 H 2 O ( l ) → C 12 H 22 O 11 ( s ) + 12 O 2 ( g ) Δ H = 5640 KJ calculate the percentage of sunlight used to produce the sucrose—that is, determine the efficiency of photosynthesis.
Solution Summary: The author explains that the energy change of a reaction is related to the enthalpy change.
The sun supplies energy at a rate of about 1.0 kilowatt per square meter of surface area (1 watt = 1 J/s). The plants in an agricultural field produce the equivalent of 20. kg sucrose (C12H22O1l) per hour per hectare (1 ha = 10.000 m2). Assuming that sucrose is produced by the reaction
12
CO
2
(
g
)
+
11
H
2
O
(
l
)
→
C
12
H
22
O
11
(
s
)
+
12
O
2
(
g
)
Δ
H
=
5640
KJ
calculate the percentage of sunlight used to produce the sucrose—that is, determine the efficiency of photosynthesis.
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
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