INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 2818000163285
Author: CORWIN
Publisher: PEARSON CO
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Chapter 7, Problem 10CE
Interpretation Introduction
Interpretation:
The product forms by heating a metal carbonate is to be stated.
Concept introduction:
A
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Students have asked these similar questions
When N,N-dimethylaniline is treated with bromine both the ortho and para products
are observed. However when treated with a mixture of nitric acid and sulfuric acid only
the meta product is observed. Explain these results and support your answer with the
appropriate drawings *Hint amines are bases*
N
HNO3
H2SO4
N
NO2
N
Br2
N
Br
+
N
8-8-8
FeBr3
Br
Draw a mechanism that explains the formation of compound
OMe
SO3H
1. Fuming H2SO4
Consider the following two acid-base reactions:
OH
OHI
Based on what you know about the compounds and their acidity, which
direction would you expect both of these reactions to proceed? Show
your reasoning.
A pKa table has been provided in case you need it.
Functional group
Example
pka
CHA
-50
Alkane
-35
Amine
: NH3
Alkyne
RH
25
Water
HO-H
169
16
10
Protonated
amines
NH
10
5
Carboxylic
acids
OH
Hydrochloric
acid
HCI
A chemist intends to run the following reaction on the three substrates shown below:
H₂O
R-CI
product
room temp.
Cl
Cl
(1)
(2)
(3)
They find one will react quickly, one slowly, and one will not react at all. Which is which, and why?
HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?
Chapter 7 Solutions
INTRODUCTORY CHEMISTRY
Ch. 7 - Prob. 1CECh. 7 - Prob. 2CECh. 7 - Prob. 3CECh. 7 - Prob. 4CECh. 7 - Prob. 5CECh. 7 - Prob. 6CECh. 7 - Prob. 7CECh. 7 - Prob. 8CECh. 7 - Prob. 9CECh. 7 - Prob. 10CE
Ch. 7 - Prob. 11CECh. 7 - Prob. 12CECh. 7 - Prob. 13CECh. 7 - Prob. 14CECh. 7 - Prob. 15CECh. 7 - Prob. 16CECh. 7 - Prob. 1KTCh. 7 - Prob. 2KTCh. 7 - Prob. 3KTCh. 7 - Prob. 4KTCh. 7 - Prob. 5KTCh. 7 - Prob. 6KTCh. 7 - Prob. 7KTCh. 7 - Prob. 8KTCh. 7 - Prob. 9KTCh. 7 - Prob. 10KTCh. 7 - Prob. 11KTCh. 7 - Prob. 12KTCh. 7 - Prob. 13KTCh. 7 - Prob. 14KTCh. 7 - Prob. 15KTCh. 7 - Prob. 16KTCh. 7 - Prob. 17KTCh. 7 - Prob. 18KTCh. 7 - Prob. 19KTCh. 7 - Prob. 20KTCh. 7 - Prob. 21KTCh. 7 - Prob. 22KTCh. 7 - Prob. 1ECh. 7 - Prob. 2ECh. 7 - Prob. 3ECh. 7 - Prob. 4ECh. 7 - Prob. 5ECh. 7 - Prob. 6ECh. 7 - Prob. 7ECh. 7 - Prob. 8ECh. 7 - Prob. 9ECh. 7 - Prob. 10ECh. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Prob. 16ECh. 7 - Prob. 17ECh. 7 - Prob. 18ECh. 7 - Prob. 19ECh. 7 - Prob. 20ECh. 7 - Prob. 21ECh. 7 - Prob. 22ECh. 7 - Prob. 23ECh. 7 - Prob. 24ECh. 7 - Prob. 25ECh. 7 - Prob. 26ECh. 7 - Prob. 27ECh. 7 - Prob. 28ECh. 7 - Prob. 29ECh. 7 - Prob. 30ECh. 7 - Prob. 31ECh. 7 - Prob. 32ECh. 7 - Prob. 33ECh. 7 - Prob. 34ECh. 7 - Prob. 35ECh. 7 - Prob. 36ECh. 7 - Prob. 37ECh. 7 - Prob. 38ECh. 7 - Prob. 39ECh. 7 - Prob. 40ECh. 7 - Prob. 41ECh. 7 - Prob. 42ECh. 7 - Prob. 43ECh. 7 - Prob. 44ECh. 7 - Prob. 45ECh. 7 - Prob. 46ECh. 7 - Prob. 47ECh. 7 - Prob. 48ECh. 7 - Prob. 49ECh. 7 - Prob. 50ECh. 7 - Prob. 51ECh. 7 - Prob. 52ECh. 7 - Prob. 53ECh. 7 - Prob. 54ECh. 7 - Prob. 55ECh. 7 - Prob. 56ECh. 7 - Prob. 57ECh. 7 - Prob. 58ECh. 7 - Prob. 59ECh. 7 - Prob. 60ECh. 7 - Prob. 61ECh. 7 - Prob. 62ECh. 7 - Prob. 63ECh. 7 - Prob. 64ECh. 7 - Prob. 65ECh. 7 - Prob. 66ECh. 7 - Prob. 67ECh. 7 - Prob. 68ECh. 7 - Prob. 69ECh. 7 - Prob. 70ECh. 7 - Prob. 71ECh. 7 - Prob. 72ECh. 7 - Prob. 73ECh. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - Prob. 76ECh. 7 - Prob. 77ECh. 7 - Prob. 78ECh. 7 - Prob. 79ECh. 7 - Prob. 80ECh. 7 - Prob. 81ECh. 7 - Prob. 82ECh. 7 - Prob. 83ECh. 7 - Prob. 84ECh. 7 - Prob. 85ECh. 7 - Prob. 86ECh. 7 - Prob. 87ECh. 7 - Prob. 88ECh. 7 - Prob. 1STCh. 7 - Prob. 2STCh. 7 - Prob. 3STCh. 7 - Prob. 4STCh. 7 - Prob. 5STCh. 7 - Prob. 6STCh. 7 - Prob. 7STCh. 7 - Prob. 8STCh. 7 - Prob. 9STCh. 7 - Prob. 10STCh. 7 - Prob. 11STCh. 7 - Prob. 12STCh. 7 - Prob. 13STCh. 7 - Prob. 14STCh. 7 - Prob. 15STCh. 7 - Prob. 16STCh. 7 - Prob. 17STCh. 7 - Prob. 18ST
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