ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Chapter 6.9, Problem 6.15P

(a)

Interpretation Introduction

To determine: The usage of SN2 reaction in the conversion of 1chlorobutane into butan1ol.

Interpretation: The usage of SN2 reaction in the conversion of 1chlorobutane into butan1ol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as SN2 reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(b)

Interpretation Introduction

To determine: The usage of SN2 reaction in the conversion of 1chlorobutane into 1-fluorobutane.

Interpretation: The usage of SN2 reaction in the conversion of 1chlorobutane into 1-fluorobutane is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as SN2 reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(c)

Interpretation Introduction

To determine: The usage of SN2 reaction in the conversion of 1chlorobutane into 1-iodobutane.

Interpretation: The usage of SN2 reaction in the conversion of 1chlorobutane into 1-iodobutane is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as SN2 reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(d)

Interpretation Introduction

To determine: The usage of SN2 reaction in the conversion of 1chlorobutane into CH3(CH2)3CN.

Interpretation: The usage of SN2 reaction in the conversion of 1chlorobutane into CH3(CH2)3CN is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as SN2 reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(e)

Interpretation Introduction

To determine: The usage of SN2 reaction in the conversion of 1chlorobutane into the given alkyne compound.

Interpretation: The usage of SN2 reaction in the conversion of 1chlorobutane into the given alkyne compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as SN2 reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(f)

Interpretation Introduction

To determine: The usage of SN2 reaction in the conversion of 1chlorobutane into CH3CH2O(CH2)3CH3.

Interpretation: The usage of SN2 reaction in the conversion of 1chlorobutane into CH3CH2O(CH2)3CH3 is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as SN2 reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(g)

Interpretation Introduction

To determine: The usage of SN2 reaction in the conversion of 1chlorobutane into CH3(CH2)3NH2.

Interpretation: The usage of SN2 reaction in the conversion of 1chlorobutane into CH3(CH2)3NH2 is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as SN2 reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Chapter 6 Solutions

ORGANIC CHEMISTRY

Ch. 6.7 - Prob. 6.11PCh. 6.7 - Prob. 6.12PCh. 6.8 - Prob. 6.13PCh. 6.9 - Predict the major products of the following...Ch. 6.9 - Prob. 6.15PCh. 6.10A - Prob. 6.16PCh. 6.11A - When diethyl ether (CH3CH2OCH2CH3) is treated with...Ch. 6.11B - Prob. 6.18PCh. 6.11B - For each pair of compounds, state which compound...Ch. 6.12 - Prob. 6.20PCh. 6.12 - Under appropriate conditions...Ch. 6.13 - Propose an SN1 mechanism for the solvolysis of...Ch. 6.13B - Prob. 6.23PCh. 6.13B - 3-Bromocyclohexene is a secondary halide, and...Ch. 6.15 - Prob. 6.25PCh. 6.15 - Prob. 6.26PCh. 6.16 - For each reaction, give the expected substitution...Ch. 6.16 - Prob. 6.28PCh. 6.16 - Prob. 6.29PCh. 6 - Prob. 6.30SPCh. 6 - Draw the structures of the following compounds. a....Ch. 6 - Give systematic (IUPAC) names for the following...Ch. 6 - Prob. 6.33SPCh. 6 - Predict the compound in each pair that will...Ch. 6 - Prob. 6.35SPCh. 6 - Give two syntheses for (CH3)2CHOCH2CH3, and...Ch. 6 - Prob. 6.37SPCh. 6 - Prob. 6.38SPCh. 6 - Chlorocyclohexane reacts with sodium cyanide...Ch. 6 - Give the substitution products expected from...Ch. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Two of the carbocations in Problem6-42 are prone...Ch. 6 - Prob. 6.44SPCh. 6 - Predict the products of the following SN2...Ch. 6 - Prob. 6.46SPCh. 6 - Strawberry growers have used large quantities of...Ch. 6 - A solution of pure (S)-2-iodobutane ([]=+15.90) in...Ch. 6 - Prob. 6.49SPCh. 6 - Give a mechanism to explain the two products...Ch. 6 - Prob. 6.51SPCh. 6 - Because the SN1 reaction goes through a flat...Ch. 6 - Prob. 6.53SPCh. 6 - Furfuryl chloride can undergo substitution by both...Ch. 6 - Prob. 6.55SPCh. 6 - The following reaction takes place under...Ch. 6 - Propose mechanisms to account for the observed...Ch. 6 - Prob. 6.58SPCh. 6 - Prob. 6.59SP
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