ORGANIC CHEMISTRY (LOOSELEAF)
ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Chapter 6.9, Problem 22P
Interpretation Introduction

(a)

Interpretation: Whether the given statement is true for a reaction with Keq=0.8 and Ea=80kJ/mol is to be stated. The false statement is to be corrected.

Concept introduction: The activation energy (Ea) aids in determining the rate of the chemical reactions. The small value of Ea exhibits that less energy is required to convert the reactants into products. It results in the increases of a rate of reaction.

The change in Gibbs free energy, enthalpy and entropy is represented by ΔG°, ΔH° and ΔS° respectively. They are state functions. The relation ΔG° with ΔH° and ΔS° is shown as,

ΔG°=ΔH°TΔS°

The change in Gibbs free energy describes the spontaneity of the reaction. The change in enthalpy describes the relative bond strength in the substance, whereas the change in entropy describes the randomness in the system.

Interpretation Introduction

(b)

Interpretation: Whether the given statement is true for a reaction with Keq=0.8 and Ea=80kJ/mol is to be stated. The false statement is to be corrected.

Concept introduction: The activation energy (Ea) aids in determining the rate of the chemical reactions. The small value of Ea exhibits that less energy is required to convert the reactants into products. It results in the increases of a rate of reaction.

The change in Gibbs free energy, enthalpy and entropy is represented by ΔG°, ΔH° and ΔS° respectively. They are state functions. The relation ΔG° with ΔH° and ΔS° is shown as,

ΔG°=ΔH°TΔS°

The change in Gibbs free energy describes the spontaneity of the reaction. The change in enthalpy describes the relative bond strength in the substance, whereas the change in entropy describes the randomness in the system.

Interpretation Introduction

(c)

Interpretation: Whether the given statement is true for a reaction with Keq=0.8 and Ea=80kJ/mol is to be stated. The false statement is to be corrected.

Concept introduction: The activation energy (Ea) aids in determining the rate of the chemical reactions. The small value of Ea exhibits that less energy is required to convert the reactants into products. It results in the increases of a rate of reaction.

The change in Gibbs free energy, enthalpy and entropy is represented by ΔG°, ΔH° and ΔS° respectively. They are state functions. The relation ΔG° with ΔH° and ΔS° is shown as,

ΔG°=ΔH°TΔS°

The change in Gibbs free energy describes the spontaneity of the reaction. The change in enthalpy describes the relative bond strength in the substance, whereas the change in entropy describes the randomness in the system.

Interpretation Introduction

(d)

Interpretation: Whether the given statement is true for a reaction with Keq=0.8 and Ea=80kJ/mol is to be stated. The false statement is to be corrected.

Concept introduction: The activation energy (Ea) aids in determining the rate of the chemical reactions. The small value of Ea exhibits that less energy is required to convert the reactants into products. It results in the increases of a rate of reaction.

The change in Gibbs free energy, enthalpy and entropy is represented by ΔG°, ΔH° and ΔS° respectively. They are state functions. The relation ΔG° with ΔH° and ΔS° is shown as,

ΔG°=ΔH°TΔS°

The change in Gibbs free energy describes the spontaneity of the reaction. The change in enthalpy describes the relative bond strength in the substance, whereas the change in entropy describes the randomness in the system.

Interpretation Introduction

(e)

Interpretation: Whether the given statement is true for a reaction with Keq=0.8 and Ea=80kJ/mol is to be stated. The false statement is to be corrected.

Concept introduction: The activation energy (Ea) aids in determining the rate of the chemical reactions. The small value of Ea exhibits that less energy is required to convert the reactants into products. It results in the increases of a rate of reaction.

The change in Gibbs free energy, enthalpy and entropy is represented by ΔG°, ΔH° and ΔS° respectively. They are state functions. The relation ΔG° with ΔH° and ΔS° is shown as,

ΔG°=ΔH°TΔS°

The change in Gibbs free energy describes the spontaneity of the reaction. The change in enthalpy describes the relative bond strength in the substance, whereas the change in entropy describes the randomness in the system.

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