It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift. Concept introduction: The stability order of carbocation is methyl < primary < secondary < tertiary. The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon. The selection of hydride or methyl group shift depends on the stability of carbocation formed.

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Answer 1

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Chapter 6.8, Problem 12P

Interpretation Introduction

Interpretation:

It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift.

Concept introduction:

The stability order of carbocation is methyl < primary < secondary < tertiary.

The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon.

The selection of hydride or methyl group shift depends on the stability of carbocation formed.

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Answer 2

Question

Chapter 6.8, Problem 12P

Interpretation Introduction

Interpretation:

It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift.

Concept introduction:

The stability order of carbocation is methyl < primary < secondary < tertiary.

The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon.

The selection of hydride or methyl group shift depends on the stability of carbocation formed.

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Answer 3

Question

Chapter 6.8, Problem 12P

Interpretation Introduction

Interpretation:

It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift.

Concept introduction:

The stability order of carbocation is methyl < primary < secondary < tertiary.

The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon.

The selection of hydride or methyl group shift depends on the stability of carbocation formed.

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Answer 4

Question

Chapter 6.8, Problem 12P

Interpretation Introduction

Interpretation:

It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift.

Concept introduction:

The stability order of carbocation is methyl < primary < secondary < tertiary.

The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon.

The selection of hydride or methyl group shift depends on the stability of carbocation formed.

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Answer 5

Chapter 6.8, Problem 12P

Interpretation Introduction

Interpretation:

It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift.

Concept introduction:

The stability order of carbocation is methyl < primary < secondary < tertiary.

The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon.

The selection of hydride or methyl group shift depends on the stability of carbocation formed.

Answer 6

Chapter 6.8, Problem 12P

Interpretation Introduction

Interpretation:

It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift.

Concept introduction:

The stability order of carbocation is methyl < primary < secondary < tertiary.

The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon.

The selection of hydride or methyl group shift depends on the stability of carbocation formed.

Answer 7

Chapter 6.8, Problem 12P

Interpretation Introduction

Interpretation:

It is to be explained that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by a hydride shift rather than a methyl shift.

Concept introduction:

The stability order of carbocation is methyl < primary < secondary < tertiary.

The carbocation can be stabilized by rearrangement due to shift of hydride or methyl group of adjacent carbon.

The selection of hydride or methyl group shift depends on the stability of carbocation formed.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 6.1 - Prob. 1P Ch. 6.2 - 1-Bromo-3-chloropropane reacts with one molar...Ch. 6.3 - Prob. 3P Ch. 6.3 - The Fischer projection for (+)-2-bromooctane is...Ch. 6.3 - Would you expect the 2-octanol formed by SN2...Ch. 6.3 - Prob. 6P Ch. 6.4 - Prob. 7P Ch. 6.4 - The first step in the synthesis of the...Ch. 6.6 - Prob. 9P Ch. 6.6 - Prob. 10P

Solution Summary: The author explains that the carbocation intermediate in the hydrolysis of 2-bromo-3-methylbutane rearranges by hydride shift rather than methyl shift.

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