Reactants X and product Y in the given sequence of reactions is to be determined. Concept Introduction: Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines , etc... In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group. Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached. The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates. If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule. The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the S N 2 mechanism pathway.

Question

Want to see the full answer?

Answer 1

Question

Chapter 6, Problem 45DSP

Interpretation Introduction

Interpretation:

Reactants X and product Y in the given sequence of reactions is to be determined.

Concept Introduction:

Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines, etc...

In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group.

Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached.

The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates.

If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule.

The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the SN2 mechanism pathway.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Draw the following molecule: (Z)-1-chloro-1-butene

Identify the molecule as having a(n) E, Z, cis, or trans configuration. CH3 H₁₂C ○ E ○ z ○ cis trans

Identify the molecule as having a(n) E, Z, cis, or trans configuration. H₂C- CH3 О Е ○ cis ○ trans

Answer 2

Question

Chapter 6, Problem 45DSP

Interpretation Introduction

Interpretation:

Reactants X and product Y in the given sequence of reactions is to be determined.

Concept Introduction:

Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines, etc...

In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group.

Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached.

The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates.

If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule.

The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the SN2 mechanism pathway.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 6, Problem 45DSP

Interpretation Introduction

Interpretation:

Reactants X and product Y in the given sequence of reactions is to be determined.

Concept Introduction:

Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines, etc...

In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group.

Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached.

The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates.

If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule.

The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the SN2 mechanism pathway.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 6, Problem 45DSP

Interpretation Introduction

Interpretation:

Reactants X and product Y in the given sequence of reactions is to be determined.

Concept Introduction:

Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines, etc...

In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group.

Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached.

The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates.

If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule.

The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the SN2 mechanism pathway.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 6, Problem 45DSP

Interpretation Introduction

Interpretation:

Reactants X and product Y in the given sequence of reactions is to be determined.

Concept Introduction:

Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines, etc...

In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group.

Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached.

The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates.

If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule.

The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the SN2 mechanism pathway.

Answer 6

Chapter 6, Problem 45DSP

Interpretation Introduction

Interpretation:

Reactants X and product Y in the given sequence of reactions is to be determined.

Concept Introduction:

Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines, etc...

In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group.

Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached.

The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates.

If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule.

The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the SN2 mechanism pathway.

Answer 7

Chapter 6, Problem 45DSP

Interpretation Introduction

Interpretation:

Reactants X and product Y in the given sequence of reactions is to be determined.

Concept Introduction:

Alkyl sulfonates are prepared by the reaction of an alcohol with sulfonyl chlorides. These reactions are carried out in suitable solvents such as trimethylamine, amines, etc...

In these reactions, the hydrogen atom of the hydroxyl group in alcohols is substituted by the methyl sulfonate group.

Their preparation comprises the oxygen of the alcohol and not the carbon to which the oxygen is attached.

The stereochemistry of the original alcohol and the carbon skeleton both are maintained when the alcohols are converted to their corresponding alkyl sulfonates.

If the structure for the product molecule is known, the corresponding reactant alcohol can be found by replacing the methyl sulfonate group by the hydrogen atom without changing the stereochemistry of the alcohol molecule.

The reaction of this methane sulfonate with sodium azide produces the corresponding alkyl azide, and this reaction follows the SN2 mechanism pathway.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 6.1 - Prob. 1P Ch. 6.2 - 1-Bromo-3-chloropropane reacts with one molar...Ch. 6.3 - Prob. 3P Ch. 6.3 - The Fischer projection for (+)-2-bromooctane is...Ch. 6.3 - Would you expect the 2-octanol formed by SN2...Ch. 6.3 - Prob. 6P Ch. 6.4 - Prob. 7P Ch. 6.4 - The first step in the synthesis of the...Ch. 6.6 - Prob. 9P Ch. 6.6 - Prob. 10P

Solution Summary: The author explains how the reaction of an alcohol with sulfonyl chlorides produces alkyl para-tolunes

Want to see the full answer?

Chapter 6 Solutions