ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
4th Edition
ISBN: 9781119745105
Author: Klein
Publisher: WILEY
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Chapter 6.8, Problem 11PTS

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation:

  ORGANIC CHEMISTRY, Chapter 6.8, Problem 11PTS , additional homework tip  1

Concept introduction: Intermediates like the carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:

Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

  ORGANIC CHEMISTRY, Chapter 6.8, Problem 11PTS , additional homework tip  2

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:

Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

  ORGANIC CHEMISTRY, Chapter 6.8, Problem 11PTS , additional homework tip  3

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:

Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

  ORGANIC CHEMISTRY, Chapter 6.8, Problem 11PTS , additional homework tip  4

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:

Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.

(e)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

  ORGANIC CHEMISTRY, Chapter 6.8, Problem 11PTS , additional homework tip  5

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:

Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.

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