Concept explainers
Videos
(a)
Interpretation: The arrow pushing method is to be interpreted for the given transformation:
Concept introduction: Intermediates like the carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.
(b)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.
(c)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.
(d)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.
(e)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary This transformation can occur with the hydride shift; methylene shifts or methyl shift. The arrow pushing method helps to identify the curved arrows and transformation.
Want to see the full answer?
Check out a sample textbook solution
Chapter 6 Solutions
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
- Acetic acid is added to DI water at an initial concentration of 10 -6 M (Ka=1.8x10-5) A. Using the "ICE" Method, what would the pH be at equilibrium? State assumptions and show your work. B. Using the simultaneous equations method, what would the pH be at equilibrium? Show your workarrow_forward1. Show that the change in entropy for a fixed amount of ideal gas held at a constant temperature undergoing a volume change is given by the simple equation AS = NkB In Hint: Start with the equation M dS = du + (Œ) dv - Ž (#) an, dU du+av-dN; j=1 Why doesn't the equation for the entropy of an ideal gas depend on the strength of the intermolecular forces for the gas?arrow_forward2. Make an ice cube at 1 bar pressure by freezing an amount of liquid water that is 2 cm x 2 cm x 2 cm in volume. The density of liquid water at 0 °C is 1.000 g cm³ and the density of ice at 0 °C is 0.915 g cm³. Note that this difference in density is the reason your water pipes burst if they freeze and why you shouldn't forget to take your bottle of pop out of the freezer if you put it in there to try and cool it down faster. A. What is the work of expansion upon freezing? B. Is work done on the system or by the system?arrow_forward
- I have a excitation/emission spectra of a quinine standard solution here, and I'm having trouble interpreting it. the red line is emission the blue line is excitation. i'm having trouble interpreting properly. just want to know if there is any evidence of raman or rayleigh peaks in the spectra.arrow_forwardGive the major product of the following reaction. excess 1. OH, H₂O 1.OH H CH3CH2CH21 H 2. A.-H₂O Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.arrow_forward2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forward
- The combustion of 28.8 g of NH3 consumes exactly _____ g of O2. 4 NH3 + 7 O2 ----> 4 NO2 + 6 H2Oarrow_forwardWhat is the molecular formula of the bond-line structure shown below OH HO ○ C14H12O2 ○ C16H14O2 ○ C16H12O2 O C14H14O2arrow_forwardCheck all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forward
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
