An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 6.5, Problem 43P

Some advanced textbooks define entropy by the formula S = k s P ( s ) ln P ( s ) , where the sum runs over all microstates accessible to the system and P(s) is the probability of the system being in microstate s.

  1. For an isolated system, P ( s ) = 1 / Ω for all accessible states s. Show that in this case the preceding formula reduces to our familiar definition of entropy.
  2. For a system in thermal equilibrium with a reservoir at temperature T, P ( s ) = e E ( s ) / k T / Z . Show that in this case as well, the preceding formula agrees with what we already know about entropy.

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