CHEMISTRY: MOLECULAR...(LL) W/ALEKS
CHEMISTRY: MOLECULAR...(LL) W/ALEKS
9th Edition
ISBN: 9781265141875
Author: SILBERBERG
Publisher: MCG CUSTOM
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Chapter 6.4, Problem 6.8BFP
Interpretation Introduction

Interpretation:

The heat that is absorbed when 3.50 t of NO is formed when 180.58 kJ of heat is absorbed per mole of N2 is to be determined.

Concept introduction:

The internal energy of a process is the summation of the kinetic energy and potential energy associated with the process. In chemical reactions, the change in internal energy (ΔE) is the difference in the energy of the product and reactant but at constant pressure, the PΔV work gets eliminated and the change in enthalpy (ΔH) is measured.

In chemical reactions, the change in enthalpy (ΔH) is the difference in the energy of the product and reactant. The general expression to calculate ΔH is,

ΔH=HProductHReactant (1)

Here,

ΔH is the change in enthalpy of the system.

HProduct is the enthalpy of the products.

HReactant is the enthalpy of the reactants.

Endothermic reactions are the reactions in which energy in the form of the heat or light is absorbed by the reactant for the formation of product. HProduct is greater than HReactant in the endothermic reactions.

Exothermic reactions are the reactions in which energy in the form of the heat or light is released with the product. HReactant is greater than HProduct in the exothermic reactions.

The conversion factor to convert metric tons (t) into kg is,

1t=1000kg

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What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.

Chapter 6 Solutions

CHEMISTRY: MOLECULAR...(LL) W/ALEKS

Ch. 6.3 - When 25.0 mL of 2.00 M HNO3 and 50.0 mL of 1.00 M...Ch. 6.3 - Prob. 6.6BFPCh. 6.3 - Prob. 6.7AFPCh. 6.3 - Prob. 6.7BFPCh. 6.4 - Prob. 6.8AFPCh. 6.4 - Prob. 6.8BFPCh. 6.5 - Prob. 6.9AFPCh. 6.5 - Prob. 6.9BFPCh. 6.6 - Prob. 6.10AFPCh. 6.6 - Prob. 6.10BFPCh. 6.6 - Prob. 6.11AFPCh. 6.6 - Prob. 6.11BFPCh. 6 - Prob. 6.1PCh. 6 - Prob. 6.2PCh. 6 - Prob. 6.3PCh. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.7PCh. 6 - Prob. 6.8PCh. 6 - Prob. 6.9PCh. 6 - A system releases 255 cal of heat to the...Ch. 6 - What is the change in internal energy (in J) of a...Ch. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Thermal decomposition of 5.0 metric tons of...Ch. 6 - Prob. 6.15PCh. 6 - The external pressure on a gas sample is 2660...Ch. 6 - The nutritional calorie (Calorie) is equivalent to...Ch. 6 - If an athlete expends 1950 kJ/h, how long does it...Ch. 6 - Prob. 6.19PCh. 6 - Hot packs used by skiers produce heat via the...Ch. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - For each process, state whether ΔH is less than...Ch. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - What data do you need to determine the specific...Ch. 6 - Is the specific heat capacity of a substance an...Ch. 6 - Prob. 6.35PCh. 6 - Both a coffee-cup calorimeter and a bomb...Ch. 6 - Find q when 22.0 g of water is heated from 25.0°C...Ch. 6 - Calculate q when 0.10 g of ice is cooled from...Ch. 6 - A 295-g aluminum engine part at an initial...Ch. 6 - Prob. 6.40PCh. 6 - Two iron bolts of equal mass—one at 100.°C, the...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - Prob. 6.44PCh. 6 - Prob. 6.45PCh. 6 - A 30.5-g sample of an alloy at 93.0°C is placed...Ch. 6 - When 25.0 mL of 0.500 M H2SO4 is added to 25.0 mL...Ch. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - A chemist places 1.750 g of ethanol, C2H6O, in a...Ch. 6 - High-purity benzoic acid (C6H5COOH; ΔH for...Ch. 6 - Two aircraft rivets, one iron and the other...Ch. 6 - A chemical engineer burned 1.520 g of a...Ch. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Consider the following balanced thermochemical...Ch. 6 - Prob. 6.58PCh. 6 - Prob. 6.59PCh. 6 - When 1 mol of KBr(s) decomposes to its elements,...Ch. 6 - Prob. 6.61PCh. 6 - Compounds of boron and hydrogen are remarkable for...Ch. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.70PCh. 6 - Prob. 6.71PCh. 6 - Write the balanced overall equation (equation 3)...Ch. 6 - Prob. 6.73PCh. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Prob. 6.77PCh. 6 - Prob. 6.78PCh. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - Calculatefor each of the following: SiO2(s) +...Ch. 6 - Prob. 6.84PCh. 6 - Prob. 6.85PCh. 6 - The common lead-acid car battery produces a large...Ch. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Prob. 6.89PCh. 6 - Prob. 6.90PCh. 6 - Prob. 6.91PCh. 6 - Prob. 6.92PCh. 6 - The following scenes represent a gaseous reaction...Ch. 6 - Prob. 6.94PCh. 6 - Prob. 6.95PCh. 6 - Prob. 6.96PCh. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - Prob. 6.99PCh. 6 - Prob. 6.100PCh. 6 - Prob. 6.101PCh. 6 - Prob. 6.102PCh. 6 - Prob. 6.103PCh. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Prob. 6.106PCh. 6 - Liquid methanol (CH3OH) canbe used as an...Ch. 6 - Prob. 6.108P
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