From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified. To identify: The given reaction whether it is exothermic or not

Question

4. a) Give a suitable rationale for the following cyclization, stating the type of process involved (e.g. 9-endo-dig), clearly showing the mechanistic details at each step. H CO₂Me 1) NaOMe 2) H3O® CO₂Me

Answer 1

Question

Chapter 6.4, Problem 6.3CC

(a)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(b)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(c)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(d)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

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4. a) Give a suitable rationale for the following cyclization, stating the type of process involved (e.g. 9-endo-dig), clearly showing the mechanistic details at each step. H CO₂Me 1) NaOMe 2) H3O® CO₂Me

2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be catalyzed the propylene molecules must first adsorb onto the surface. In order to completely cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that have been absorbed onto the platinum surface.

Chem 141, Dr. Haefner 2. (a) Many main group oxides form acidic solutions when added to water. For example solid tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced chemical equation for this reaction. (b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-) and carbon monoxide. Write a balanced chemical equation for this reaction.

Answer 2

Question

Chapter 6.4, Problem 6.3CC

(a)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(b)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(c)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(d)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

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Answer 3

Question

Chapter 6.4, Problem 6.3CC

(a)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(b)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(c)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(d)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

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Answer 4

Question

Chapter 6.4, Problem 6.3CC

(a)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(b)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(c)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(d)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

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Answer 5

Chapter 6.4, Problem 6.3CC

(a)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(b)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(c)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

(d)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 6

Chapter 6.4, Problem 6.3CC

(a)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 7

Chapter 6.4, Problem 6.3CC

(a)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 8

(b)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 9

(b)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 10

(c)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 11

(c)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 12

(d)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 13

(d)

Interpretation Introduction

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Answer 14

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Answer 15

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Answer 25

Ch. 6.1 - Prob. 6.1E Ch. 6.1 - A solar-powered water pump has photovoltaic cells...Ch. 6.2 - A gas is enclosed in a system similar to that...Ch. 6.2 - Prob. 6.2CC Ch. 6.3 - Ammonia burns in the presence of a platinum...Ch. 6.3 - Consider the combustion (burning) of methane, CH4,...Ch. 6.4 - A propellant for rockets is obtained by mixing the...Ch. 6.4 - a. Write the thermochemical equation for the...Ch. 6.4 - Prob. 6.3CC Ch. 6.5 - How much heat evolves when 10.0 g of hydrazine...

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified. To identify: The given reaction whether it is exothermic or not

Solution Summary: The author explains that the sign of enthalpy change is positive, so the given reaction is endothermic.

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Chapter 6 Solutions

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified. To identify: The given reaction whether it is exothermic or not

Solution Summary: The author explains that the sign of enthalpy change is positive, so the given reaction is endothermic.

Interpretation: From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified. To identify: The given reaction whether it is exothermic or not

Interpretation: From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified. To identify: The given reaction whether it is exothermic or not

Interpretation: From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified. To identify: The given reaction whether it is exothermic or not

Interpretation: From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified. To identify: The given reaction whether it is exothermic or not

Chapter 6 Solutions

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not

Interpretation:

From the given reactions, exothermic reactions and of those exothermic reactions the one which is most exothermic has to be identified.

To identify: The given reaction whether it is exothermic or not