Concept explainers
(a)
Interpretation: Carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: Carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given on the basis of the positive charge on the primary, secondary, and tertiary carbon atoms of the intermediate.
(b)
Interpretation: A carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: A carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given on the basis of the positive charge on the primary, secondary, and tertiary carbon atoms of the intermediate.
(c)
Interpretation: Carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: Carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given on the basis of the positive charge on the primary, secondary, and tertiary carbon atoms of the intermediate.
(d)
Interpretation: Carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: Carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given based on the positive charge on the primary, secondary, and tertiary carbon atoms of the intermediate.
(e)
Interpretation: Carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: Carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given on the basis of the positive charge on the primary, secondary, and tertiary carbon atoms of the intermediate.
(f)
Interpretation: Carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: Carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given on the basis of the positive charge on primary, secondary, and tertiary carbon atoms of the intermediate.
(g)
Interpretation: Carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: A carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given on the basis of the positive charge on primary, secondary, and tertiary carbon atoms of the intermediate.
(h)
Interpretation: Carbocation can rearrange to form a stable carbocation. The carbocation rearrangement with a curve arrow is to be interpreted for the given carbocation.
Concept introduction: Carbocation is an intermediate that carries a positive charge on the carbon atom. It tends to rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary >Secondary >Primary
The notation to carbocation is given on the basis of the positive charge on primary, secondary and tertiary carbon atom of the intermediate.
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Chapter 6 Solutions
ORGANIC CHEMISTRY 2-SEMESTER-ACCESS
- 2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forwardci Draw the major product(s) of the following reactions: (3 pts) CH3 HNO3/H2SO4 HNO3/ H2SO4 OCH3 (1 pts)arrow_forwardProvide the product for the reactionarrow_forward
- What is the net ionic equation for the reaction between tin(IV) sulfide and nitric acid?arrow_forwardThe combustion of 28.8 g of NH3 consumes exactly _____ g of O2. 4 NH3 + 7 O2 ----> 4 NO2 + 6 H2Oarrow_forwardWhat is the molecular formula of the bond-line structure shown below OH HO ○ C14H12O2 ○ C16H14O2 ○ C16H12O2 O C14H14O2arrow_forward
- Check all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forwardFrom the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×arrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.arrow_forward
- For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)arrow_forwardShow transformation from reactant to product, step by step. *see imagearrow_forwardCheck the box if the molecule contains the listed item. *See imagearrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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