Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
3rd Edition
ISBN: 9781119320524
Author: Klein
Publisher: WILEY
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Chapter 6.1, Problem 2ATS
Interpretation Introduction

Interpretation:

ΔH0 for the conversion of compound 1 into compound 2 in the given reaction has to be determined.

Concept Introduction:

Bond dissociation enthalpy:

Bond energy or more correctly the bond dissociation enthalpy is the enthalpy change when breaking a bond in a molecule with the reactant and products in the gas phase.

ΔrH0=ΣΔH(bondsbroken)ΣΔH(bondsformed)

The neagtive value of ΔH0 suggest that the reaction is exothermic and the positive value suggest that the reaction is endothermic.

Enthalpy of formation:

Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy, Chapter 6.1, Problem 2ATS

An endothermic reaction is one that gains heat from the surroundings.

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Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy

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