Introductory Chemistry, Books a la Carte Edition & Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Introductory Chemistry Package
1st Edition
ISBN: 9780133877939
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 6, Problem 88E
Interpretation Introduction
Interpretation:
The empirical formula of the compound is to be determined.
Concept Introduction:
The empirical formula of the given compound can be determined with the help of relative masses of the elements which constitute the compound.
In order to find the empirical formula, first, find the number of moles of elements present in the compound. Followed by this, write the pseudo formula of the compound by writing the moles of each element as a subscript.
Further, dividing the subscriptby the smallersubscript.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 6 Solutions
Introductory Chemistry, Books a la Carte Edition & Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Introductory Chemistry Package
Ch. 6 - Q1. How many atoms are there in 5.8 mol helium?
a....Ch. 6 - A sample of pure silver has a mass of 155g How...Ch. 6 - How many carbon atoms are there in a 12.5kg sample...Ch. 6 - Q4. Which sample contains the greatest number of...Ch. 6 - Q5. What is the average mass (in grams) of a...Ch. 6 - Q6. How many moles of O are in 1.6 mol of?
1.6 mol...Ch. 6 - Q7. How many grams of Cl are in?
Ch. 6 - Q8. Which sample contains the greatest number of F...Ch. 6 - Q9. The compound is 35.8% A by mass. What mass of...Ch. 6 - Q10. Which compound has the highest mass percent...
Ch. 6 - What is the mass percent N in C2H8N2 ? a. 23.3% N...Ch. 6 - Q12. A compound is 52.14% C, 13.13% H, and 34.73%...Ch. 6 - A compound has the empirical formula CH2O and a...Ch. 6 - Prob. 14SAQCh. 6 - Why is chemical composition important?Ch. 6 - 2. How can you efficiently determine the number of...Ch. 6 - Prob. 3ECh. 6 - 4. How many molecules are in 1 mol of molecules?
Ch. 6 - 5. What is the mass of 1 mol of atoms for an...Ch. 6 - What is the mass of 1 mol of molecules for a...Ch. 6 - What is the mass of 1 mol of atoms of each...Ch. 6 - 8. What is the mass of 1 mol of molecules of each...Ch. 6 - 9. The subscripts in a chemical formula give...Ch. 6 - Write the conversion factors between moles of each...Ch. 6 - Prob. 11ECh. 6 - 12. What is the mathematical formula for...Ch. 6 - How are the empirical formula and the molecular...Ch. 6 - 14. Why is it important to be able to calculate an...Ch. 6 - 15. What is the empirical formula mass of a...Ch. 6 - 16. How are the molar mass and empirical formula...Ch. 6 - How many mercury atoms are in 5.8mol of mercury?Ch. 6 - How many moles of nitrogen atoms do 9.03 1023...Ch. 6 - How many atoms are in each elemental sample? a....Ch. 6 - How many moles of atoms are in each elemental...Ch. 6 - Complete the table. Element Moles Number of Atoms...Ch. 6 - 22. Complete the table.
Compound Moles Number of...Ch. 6 - Consider these definitions. 1 doz =12 1gross =144...Ch. 6 - 24. A pure copper penny contains approximately ...Ch. 6 - 25. How many moles of tin atoms are in a pure tin...Ch. 6 - 26. A lead fishing weight contains 0.12 mol of...Ch. 6 - 27. A pure gold coin contains 0.145 mol of gold....Ch. 6 - 28. A helium balloon contains 0.46 g of helium....Ch. 6 - How many moles of atoms are in each elemental...Ch. 6 - 30. What is the mass in grams of each elemental...Ch. 6 - Complete the table. Element Mole Mass Ne ____...Ch. 6 - Complete the table. Element Moles Mass Cr 0.00442...Ch. 6 - 33. Apure silver ring contains mmol (millmol) Ag....Ch. 6 - A pure gold ring contains 0.0102 mmol (millmol)...Ch. 6 - How many aluminum atoms are in 3.78 g of aluminum?Ch. 6 - 36. What is the mass of platinum atoms?
Ch. 6 - How many atoms are in each elemental sample? a....Ch. 6 - Calculate the mass in grams of each elemental...Ch. 6 - 39. How many carbon atoms are in a diamond (pure...Ch. 6 - 41. How many titanium atoms are in a pure titanium...Ch. 6 - 42. How many copper atoms are in a pure copper...Ch. 6 - 43. Complete the table.
Element Mass Moles Number...Ch. 6 - 44. Complete the table.
Element Mass Moles Number...Ch. 6 - Which sample contains the greatest number of...Ch. 6 - Which sample contains the greatest number of...Ch. 6 - 47. Determine the number of moles of molecules (or...Ch. 6 - 48. Determine the mass of each sample.
a. mol...Ch. 6 - 49. Complete the table.
Compound Mass Moles Number...Ch. 6 - 50. Complete the table.
Compound Mass Moles Number...Ch. 6 - A mothball, composed of naphthalene (C10H8), has a...Ch. 6 - Calculate the mass in grams of a single water...Ch. 6 -
53. How many molecules are in each sample?
a.
b....Ch. 6 - Prob. 54ECh. 6 - A normal bathtub has a capacity of 150 liters. How...Ch. 6 - A salt crystal has a mass of 0.12 mg. How many...Ch. 6 - How much money, in dollars, dose 1 mol of pennies...Ch. 6 - A typical dust particle has a diameter of about...Ch. 6 - 59. Determine the number of moles of in mol .
Ch. 6 - 60. How many moles of O are in mol ?
Ch. 6 - 61. Which sample contains the greatest number of...Ch. 6 - Prob. 62ECh. 6 - Determine the number of moles of C in each sample....Ch. 6 - Determine the number of moles of H in each sample....Ch. 6 - 65. For each set of molecular models, write a...Ch. 6 - 66. For each set of molecular models, write a...Ch. 6 - 67. How many grams of are in 38.0 g of each...Ch. 6 - 68. Calculate the number of grams of sodium in...Ch. 6 - Iron is found in Earths crust as several different...Ch. 6 - 70. Lead is found in Earth’s crust as several lead...Ch. 6 - A 2.45-g sample of strontium completely reacts...Ch. 6 - A 4.78-g sample of aluminum completely reacts with...Ch. 6 - A 1.912g sample of calcium chloride is decomposed...Ch. 6 - Prob. 74ECh. 6 - When crystallized from water, copper(II) sulfate...Ch. 6 - The purity of gold is measured in carats. A...Ch. 6 - In small amounts, the fluoride ion (often consumed...Ch. 6 - The iodide ion, usually consumed as potassium...Ch. 6 - Calculate the mass percent composition of oxygen...Ch. 6 - Calculate the mass percent composition of carbon...Ch. 6 - 81. Calculate the mass percent composition of each...Ch. 6 - 82. Calculate the mass percent composition of each...Ch. 6 - 83. Calculate the mass percent composition of O in...Ch. 6 - Calculate the mass percent composition of Cl in...Ch. 6 - Various iron ores have different amounts of iron...Ch. 6 - 86. Plats need nitrogen to grow, so many...Ch. 6 - Prob. 87ECh. 6 - Prob. 88ECh. 6 - 89. Samples of several compounds are decomposed,...Ch. 6 - Samples of several compounds are decomposed, and...Ch. 6 - 91. The rotten smell of a decaying animal carcass...Ch. 6 - 92. Citric acid, the compound responsible for the...Ch. 6 - 93. These compounds are found in many natural...Ch. 6 - 94. Calculate the empirical formula for each...Ch. 6 - 95. A sample of phosphorus burns in air and forms...Ch. 6 - A 2.241-g sample of nickel reacts with oxygen to...Ch. 6 - A sample of nitrogen reacts with chlorine to form...Ch. 6 - 98. A sample of phosphorus reacts with selenium...Ch. 6 - 99. A compound containing carbon and hydrgen has a...Ch. 6 - A sulfur-nitrogen ring compound has a molar mass...Ch. 6 - 101. The molar masses and empirical formulas of...Ch. 6 - The molar masses and empirical formulas of several...Ch. 6 - 103. A. pure copper cube has an edge length of...Ch. 6 - Prob. 104ECh. 6 - A drop of water has a volume of approximately 0.05...Ch. 6 - Fingernail-polish remover is primarily acetone...Ch. 6 - 107. Complete the...Ch. 6 - Prob. 108ECh. 6 - Determine the chemical formula of each compound...Ch. 6 - Prob. 110ECh. 6 - Prob. 111ECh. 6 - A particular brand of fertilizer contains 37.6 g...Ch. 6 - 113. A leak in the air conditioning system of an...Ch. 6 - 114. A leak in the air conditioning system of an...Ch. 6 - 115. Hydrogen is a possible future fuel. However,...Ch. 6 - Prob. 116ECh. 6 - Complete the table of compounds that contain only...Ch. 6 - 118. Complete the table of compounds that contain...Ch. 6 - Butanedione, a component of butter and body odor,...Ch. 6 - 120. Caffeine, a stimulant found in coffee and...Ch. 6 - 121. Nicotine, a stimulant found tobacco, has the...Ch. 6 - Prob. 122ECh. 6 - 123. A sample contains both KBr and KI in unknown...Ch. 6 - Prob. 124ECh. 6 - Ethanethiol (C2H6S) is a compound with a...Ch. 6 - 126. Methanethiol has a disagreeable odor and is...Ch. 6 - Prob. 127ECh. 6 - Prob. 128ECh. 6 - you can use the concepts in this chapter to obtain...Ch. 6 - Prob. 130ECh. 6 - 131. In 1996, the media reported that possible...Ch. 6 - 132. Using grammatically correct English...
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