Concept explainers
Videos
(a)
Interpretation:
Total number of atoms in
Concept Introduction:
Statement that uses chemical symbols and formulas instead of words in order to describe the changes that takes place in a
- Correct formulas of the reactants are written in left side of chemical equation.
- Correct formulas of products are written in right side of chemical equation.
- An arrow is placed between reactants and products which point towards the products.
- If two or more substances are present in reactant and product, plus sign is used to separate them.
Balanced chemical equation is the one that has equal number of atoms of each element that is involved in the chemical reaction on both sides of the chemical equation. An unbalanced chemical equation can be balanced by adding coefficients to the equation. It is a number that is placed in left side of the chemical formula so that it changes the amount only and not the identity.
(b)
Interpretation:
Total number of atoms in
Concept Introduction:
Statement that uses chemical symbols and formulas instead of words in order to describe the changes that takes place in a chemical reaction is known as chemical equation. Reactants are the substances that are present in starting of the chemical reaction and it is entered in left side of the chemical equation. Products are the substance that is obtained from the reactants as a final outcome of the chemical reaction and it is entered in right side of the chemical equation. In order to write a chemical equation four conventions are used and they are,
- Correct formulas of the reactants are written in left side of chemical equation.
- Correct formulas of products are written in right side of chemical equation.
- An arrow is placed between reactants and products which point towards the products.
- If two or more substances are present in reactant and product, plus sign is used to separate them.
Balanced chemical equation is the one that has equal number of atoms of each element that is involved in the chemical reaction on both sides of the chemical equation. An unbalanced chemical equation can be balanced by adding coefficients to the equation. It is a number that is placed in left side of the chemical formula so that it changes the amount only and not the identity.
(c)
Interpretation:
Total number of atoms in
Concept Introduction:
Statement that uses chemical symbols and formulas instead of words in order to describe the changes that takes place in a chemical reaction is known as chemical equation. Reactants are the substances that are present in starting of the chemical reaction and it is entered in left side of the chemical equation. Products are the substance that is obtained from the reactants as a final outcome of the chemical reaction and it is entered in right side of the chemical equation. In order to write a chemical equation four conventions are used and they are,
- Correct formulas of the reactants are written in left side of chemical equation.
- Correct formulas of products are written in right side of chemical equation.
- An arrow is placed between reactants and products which point towards the products.
- If two or more substances are present in reactant and product, plus sign is used to separate them.
Balanced chemical equation is the one that has equal number of atoms of each element that is involved in the chemical reaction on both sides of the chemical equation. An unbalanced chemical equation can be balanced by adding coefficients to the equation. It is a number that is placed in left side of the chemical formula so that it changes the amount only and not the identity.
(d)
Interpretation:
Total number of atoms in
Concept Introduction:
Statement that uses chemical symbols and formulas instead of words in order to describe the changes that takes place in a chemical reaction is known as chemical equation. Reactants are the substances that are present in starting of the chemical reaction and it is entered in left side of the chemical equation. Products are the substance that is obtained from the reactants as a final outcome of the chemical reaction and it is entered in right side of the chemical equation. In order to write a chemical equation four conventions are used and they are,
- Correct formulas of the reactants are written in left side of chemical equation.
- Correct formulas of products are written in right side of chemical equation.
- An arrow is placed between reactants and products which point towards the products.
- If two or more substances are present in reactant and product, plus sign is used to separate them.
Balanced chemical equation is the one that has equal number of atoms of each element that is involved in the chemical reaction on both sides of the chemical equation. An unbalanced chemical equation can be balanced by adding coefficients to the equation. It is a number that is placed in left side of the chemical formula so that it changes the amount only and not the identity.
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Chapter 6 Solutions
General, Organic, and Biological Chemistry
- R₂ R₁ R₁ a R Rg Nu R₂ Rg R₁ R R₁₂ R3 R R Nu enolate forming R₁ R B-Alkylated carbonyl species or amines Cyclic B-Ketoester R₁₁ HOB R R₁B R R₁₂ B-Hydroxy carbonyl R diester R2 R3 R₁ RB OR R₂ 0 aB-Unsaturated carbonyl NaOR Aldol HOR reaction 1) LDA 2) R-X 3) H₂O/H₂O ketone, aldehyde 1) 2°-amine 2) acid chloride 3) H₂O'/H₂O 0 O R₁ R₁ R R₁ R₁₂ Alkylated a-carbon R₁ H.C R₁ H.C Alkylated methyl ketone acetoacetic ester B-Ketoester ester R₁ HO R₂ R B-Dicarbonyl HO Alkylated carboxylic acid malonic ester Write the reagents required to bring about each reaction next to the arrows shown. Next, record any regiochemistry or stereochemistry considerations relevant to the reaction. You should also record any key aspects of the mechanism, such as forma- tion of an important intermediate, as a helpful reminder. You may want to keep track of all reactions that make carbon-carbon bonds, because these help you build large molecules from smaller fragments. This especially applies to the reactions in…arrow_forwardProvide the reasonable steps to achieve the following synthesis.arrow_forwardIdentify which compound is more acidic. Justify your choice.arrow_forward
- Provide the reasonable steps to achieve the following synthesis.arrow_forwardWhen anisole is treated with excess bromine, the reaction gives a product which shows two singlets in 1H NMR. Draw the product.arrow_forward(ii) Draw a reasonable mechanism for the following reaction: CI NaOH heat OH (hint: SNAr Reaction) :arrow_forward
- For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardConsider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forward
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