(a) Interpretation: The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified. Concept introduction: An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 1

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

Indicate the rate expressions for reactions that have order 0, 1, and 2.

PROBLEMS Q1) Label the following salts as either acidic, basic, or neutral a) Fe(NOx) c) AlBr b) NH.CH COO d) HCOON (1/2 mark each) e) Fes f) NaBr Q2) What is the pH of a 0.0750 M solution of sulphuric acid?

Answer 2

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 3

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 4

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 5

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 6

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 7

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 6 - Prob. 6.1P Ch. 6 - Prob. 6.2P Ch. 6 - Prob. 6.3P Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Solution Summary: The author explains that asymmetric centers in omeprazole can be resolved into enantiomers.

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