The way in which the inversion rate of arsines would be compared with that of amines and phosphines is to be stated. The explanation for the corresponding answer is to be stated. Concept introduction: The periodic table represents elements in order of their atomic numbers. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. The electrons are arranged in the subshell of atoms according to their increasing energies. The orbital with lower energy will fill first than the orbital with higher energy.

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Chapter 6, Problem 6.23P

Interpretation Introduction

Interpretation:

The way in which the inversion rate of arsines would be compared with that of amines and phosphines is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The periodic table represents elements in order of their atomic numbers. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. The electrons are arranged in the subshell of atoms according to their increasing energies. The orbital with lower energy will fill first than the orbital with higher energy.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai