(a) Interpretation: The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified. Concept introduction: An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 1

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Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 3

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 4

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 5

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 6

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 7

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 12

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Answer 13

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Answer 15

Ch. 6 - Prob. 6.1P Ch. 6 - Prob. 6.2P Ch. 6 - Prob. 6.3P Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Solution Summary: The author explains that asymmetric centers in omeprazole can be resolved into enantiomers.

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