Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 6, Problem 6.13P
Interpretation Introduction

Interpretation:

The stereochemical configuration of the product of the given reaction is to be assigned.

Concept introduction:

The naming of the chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chiral center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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