Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Textbook Question
Chapter 6, Problem 6.11QAP
Calculate the wavelength of
(a) the sodium line at 589 nm in diamond, which has a refractive index of 2.419.
(b) the output of a ruby laser at 694.3 when it is passing through a piece of acrylic sheet (Plexiglas©), which has a refractive index of 1.49.
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The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
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NH2
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CHINO₂
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Scheme 5
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Draw the structure of intermediate O.
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(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
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P.
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(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
[shom 2]
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Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
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(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 6 Solutions
Principles of Instrumental Analysis
Ch. 6 - Prob. 6.1QAPCh. 6 - Calculate the frequency in hertz, the energy in...Ch. 6 - Calculate the frequency in hertz, the wavelength...Ch. 6 - Prob. 6.4QAPCh. 6 - Prob. 6.5QAPCh. 6 - Prob. 6.6QAPCh. 6 - What is the wavelength of a photon that has three...Ch. 6 - The silver bromide bond energy is approximately...Ch. 6 - Cesium is used extensively in photocells and in...Ch. 6 - Prob. 6.10QAP
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