Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Question
Chapter 6, Problem 6.10VP
Interpretation Introduction
To predict:
Referring figure P6.12, predict if the ice under the skate edges will melt.
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Students have asked these similar questions
Consider the following decomposition reaction of N2O5(g):
For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 → NO2 + NO3 (K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 → NO2 + O2 + NO (K2)
NO + N2O5 → NO2 + NO2 + NO2 (K3)
Indicate whether the following rate expression is acceptable:
d[N2O5]
= -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³
dt
In a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.
For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 →> NO₂+ NO3_(K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 →
→
NO2 + O2 + NO (K2)
NO + N2O5-
NO2 + NO2 + NO2 (K3)
d[N₂O5] __2k‚k₂[N2O5]
Indicate whether the following rate expression is acceptable:
dt
k₁₁+ k₂
Chapter 6 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 6 - Prob. 6.1VPCh. 6 - Prob. 6.2VPCh. 6 - Prob. 6.3VPCh. 6 - Prob. 6.4VPCh. 6 - Prob. 6.5VPCh. 6 - Prob. 6.6VPCh. 6 - Prob. 6.7VPCh. 6 - Prob. 6.8VPCh. 6 - Prob. 6.9VPCh. 6 - Prob. 6.10VP
Ch. 6 - Prob. 6.11VPCh. 6 - Prob. 6.12VPCh. 6 - Prob. 6.13VPCh. 6 - Prob. 6.14VPCh. 6 - Prob. 6.15VPCh. 6 - Prob. 6.16VPCh. 6 - Prob. 6.17QACh. 6 - Prob. 6.18QACh. 6 - Prob. 6.19QACh. 6 - Prob. 6.20QACh. 6 - Prob. 6.21QACh. 6 - Prob. 6.22QACh. 6 - Prob. 6.23QACh. 6 - Prob. 6.24QACh. 6 - Prob. 6.25QACh. 6 - Prob. 6.26QACh. 6 - Prob. 6.27QACh. 6 - Prob. 6.28QACh. 6 - Prob. 6.29QACh. 6 - Prob. 6.30QACh. 6 - Prob. 6.31QACh. 6 - Prob. 6.32QACh. 6 - Prob. 6.33QACh. 6 - Prob. 6.34QACh. 6 - Prob. 6.35QACh. 6 - Prob. 6.36QACh. 6 - Prob. 6.37QACh. 6 - Prob. 6.38QACh. 6 - Prob. 6.39QACh. 6 - Prob. 6.40QACh. 6 - Prob. 6.41QACh. 6 - Prob. 6.42QACh. 6 - Prob. 6.43QACh. 6 - Prob. 6.44QACh. 6 - Prob. 6.45QACh. 6 - Prob. 6.46QACh. 6 - Prob. 6.47QACh. 6 - Prob. 6.48QACh. 6 - Prob. 6.49QACh. 6 - Prob. 6.50QACh. 6 - Prob. 6.51QACh. 6 - Prob. 6.52QACh. 6 - Prob. 6.53QACh. 6 - Prob. 6.54QACh. 6 - Prob. 6.55QACh. 6 - Prob. 6.56QACh. 6 - Prob. 6.57QACh. 6 - Prob. 6.58QACh. 6 - Prob. 6.59QACh. 6 - Prob. 6.60QACh. 6 - Prob. 6.61QACh. 6 - Prob. 6.62QACh. 6 - Prob. 6.63QACh. 6 - Prob. 6.64QACh. 6 - Prob. 6.65QACh. 6 - Prob. 6.66QACh. 6 - Prob. 6.67QACh. 6 - Prob. 6.68QACh. 6 - Prob. 6.69QACh. 6 - Prob. 6.70QACh. 6 - Prob. 6.71QACh. 6 - Prob. 6.72QACh. 6 - Prob. 6.73QACh. 6 - Prob. 6.74QA
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Similar questions
- Given the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardk₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forward
- k₁ Given the reaction R₂ R + R, indicate k-1 (A). the rate law with respect to R2: (B). the rate law with respect to R: d[R₂] dt d[R] dtarrow_forwardGiven the reaction R+ Q → P, indicate (A). the rate law with respect to P: (B). the rate law with respect to R: (C). the rate law with respect to Q: d[P] dt d[R] dt d[Q] dtarrow_forwardThe reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.arrow_forward
- a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwarda. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?arrow_forward
- When N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forwardConsider the following two acid-base reactions: OH OHI Based on what you know about the compounds and their acidity, which direction would you expect both of these reactions to proceed? Show your reasoning. A pKa table has been provided in case you need it. Functional group Example pka CHA -50 Alkane -35 Amine : NH3 Alkyne RH 25 Water HO-H 169 16 10 Protonated amines NH 10 5 Carboxylic acids OH Hydrochloric acid HCI A chemist intends to run the following reaction on the three substrates shown below: H₂O R-CI product room temp. Cl Cl (1) (2) (3) They find one will react quickly, one slowly, and one will not react at all. Which is which, and why? HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?arrow_forward
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