Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

3rd Edition

ISBN: 9780133890686

Author: Tro

Publisher: PEARSON

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Chapter 6, Problem 46E

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Chapter 6, Problem 45E

Chapter 6, Problem 47E

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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex. a) Identify if the [Cr(CN)6] anionic complex has 4 long and 2 short bonds (left side of figure) or if the complex has 4 short and 2 long bonds (right side of figure) with respect to Oh symmetry. Use crystal field theory to answer this question. Explain/rationalize your decision. Can the provided information decide on the order of orbital energies? Dah Tetragonal Distortion ய Dab z-compression z-elongation x and y elongation O symmetry x and y compression E eg d² dx²-y² t2g dxy dxz dyz Question 4 a) continued: Provide your explanations in the space below. b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc as well as the paramagnetic and…

a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if applicable). ード M 4- b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible isomers and their corresponding point groups. Use the point groups to determine if the complexes have resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if applicable). The number of complex sketches below is not necessarily indicative of the number of isomers. 4- 4- ☐☐☐ c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible isomers and their corresponding point groups.. Use the point groups to determine if the complexes have resulting net dipole…

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Chapter 6 Solutions

Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

Ch. 6 - Prob. 1SAQ Ch. 6 - Q2. Which sample is most likely to undergo the...Ch. 6 - Prob. 3SAQ Ch. 6 - Q4. A 12.5-g sample of granite initially at 82.0...Ch. 6 - Q5. A cylinder with a moving piston expands from...Ch. 6 - Q6. When a 3.80-g sample of liquid octane (C8H18)...Ch. 6 - Q7. Hydrogen gas reacts with oxygen to form...Ch. 6 - Prob. 8SAQ Ch. 6 - Prob. 9SAQ Ch. 6 - Prob. 10SAQ

Ch. 6 - Prob. 11SAQ Ch. 6 - Prob. 12SAQ Ch. 6 - Prob. 13SAQ Ch. 6 - Prob. 14SAQ Ch. 6 - Q15. Natural gas burns in air to form carbon...Ch. 6 - 1. What is thermochemistry? Why is it important? Ch. 6 - 2. What is energy? What is work? List some...Ch. 6 - Prob. 3E Ch. 6 - 4. State the law of conservation of energy. How...Ch. 6 - Prob. 5E Ch. 6 - 6. State the first law of thermodynamics. What are...Ch. 6 - Prob. 7E Ch. 6 - 8. What is a state function? List some examples of...Ch. 6 - 9. What is internal energy? Is internal energy a...Ch. 6 - 10. If energy flows out of a chemical system and...Ch. 6 - 11. If the internal energy of the products of a...Ch. 6 - 12. What is heat? Explain the difference between...Ch. 6 - 13. How is the change in internal energy of a...Ch. 6 - 14. Explain how the sum of heat and work can be a...Ch. 6 - 15. What is heat capacity? Explain the difference...Ch. 6 - 16. Explain how the high specific heat capacity of...Ch. 6 - 17. If two objects, A and B, of different...Ch. 6 - 18. What is pressure–volume work? How is it...Ch. 6 - 19. What is calorimetry? Explain the difference...Ch. 6 - 20. What is the change in enthalpy (ΔH) for a...Ch. 6 - 21. Explain the difference between an exothermic...Ch. 6 - 22. From a molecular viewpoint, where does the...Ch. 6 - 23. From a molecular viewpoint, where does the...Ch. 6 - 24. Is the change in enthalpy for a reaction an...Ch. 6 - Prob. 25E Ch. 6 - Prob. 26E Ch. 6 - 27. What is a standard state? What is the standard...Ch. 6 - Prob. 28E Ch. 6 - How do you calculate Hrxno from tabulated standard...Ch. 6 - Prob. 30E Ch. 6 - 31. What are the main environmental problems...Ch. 6 - Prob. 32E Ch. 6 - Prob. 33E Ch. 6 - Prob. 34E Ch. 6 - Prob. 35E Ch. 6 - 36. A particular frost-free refrigerator uses...Ch. 6 - 37. Which statement is true of the internal energy...Ch. 6 - Prob. 38E Ch. 6 - 39. Identify each energy exchange as primarily...Ch. 6 - 40. Identify each energy exchange as primarily...Ch. 6 - 41. A system releases 622 kJ of heat and does 105...Ch. 6 - 42. A system absorbs 196 kJ of heat and the...Ch. 6 - 43. The gas in a piston (defined as the system)...Ch. 6 - Prob. 44E Ch. 6 - Prob. 45E Ch. 6 - Prob. 46E Ch. 6 - 47. How much heat is required to warm 1.50 L of...Ch. 6 - 48. How much heat is required to warm 1.50 kg of...Ch. 6 - 49. Suppose that 25 g of each substance is...Ch. 6 - 50. An unknown mass of each substance, initially...Ch. 6 - 51. How much work (in J) is required to expand the...Ch. 6 - Prob. 52E Ch. 6 - 53. The air within a piston equipped with a...Ch. 6 - 54. A gas is compressed from an initial volume of...Ch. 6 - 55. When 1 mol of a fuel burns at constant...Ch. 6 - 56. The change in internal energy for the...Ch. 6 - 57. Determine whether each process is exothermic...Ch. 6 - 58. Determine whether each process is exothermic...Ch. 6 - 59. Consider the thermochemical equation for the...Ch. 6 - 60. What mass of natural gas (CH4) must burn to...Ch. 6 - Prob. 61E Ch. 6 - Prob. 62E Ch. 6 - 63. The propane fuel (C3H8) used in gas barbeques...Ch. 6 - Prob. 64E Ch. 6 - 65. A silver block, initially at 58.5 °C, is...Ch. 6 - Prob. 66E Ch. 6 - 67. A 31.1-g wafer of pure gold, initially at 69.3...Ch. 6 - Prob. 68E Ch. 6 - Prob. 69E Ch. 6 - 70. A 2.74-g sample of a substance suspected of...Ch. 6 - 71. Exactly 1.5 g of a fuel burns under conditions...Ch. 6 - 72. In order to obtain the largest possible amount...Ch. 6 - 73. When 0.514 g of biphenyl (C12H10) undergoes...Ch. 6 - Prob. 74E Ch. 6 - 75. Zinc metal reacts with hydrochloric acid...Ch. 6 - Prob. 76E Ch. 6 - Prob. 77E Ch. 6 - Prob. 78E Ch. 6 - 79. Calculate ΔHrxn for the reaction: Fe2O3(s) + 3...Ch. 6 - 80. Calculate ΔHrxn for the reaction: CaO(s) +...Ch. 6 - 81. Calculate ΔHrxn for the reaction: 5 C(s) + 6...Ch. 6 - 82. Calculate ΔHrxn for the reaction: CH4(g) + 4...Ch. 6 - 83. Write an equation for the formation of each...Ch. 6 - Prob. 84E Ch. 6 - 85. Hydrazine (N2H4) is a fuel used by some...Ch. 6 - Prob. 86E Ch. 6 - Prob. 87E Ch. 6 - Prob. 88E Ch. 6 - 89. During photosynthesis, plants use energy from...Ch. 6 - Prob. 90E Ch. 6 - 91. Top fuel dragsters and funny cars burn...Ch. 6 - 92. The explosive nitroglycerin (C3H5N3O9)...Ch. 6 - 93. Determine the mass of CO2 produced by burning...Ch. 6 - Prob. 94E Ch. 6 - Prob. 95E Ch. 6 - Prob. 96E Ch. 6 - Prob. 97E Ch. 6 - Prob. 98E Ch. 6 - 99. Evaporating sweat cools the body because...Ch. 6 - Prob. 100E Ch. 6 - 101. Use standard enthalpies of formation to...Ch. 6 - 102. Dry ice is solid carbon dioxide. Instead of...Ch. 6 - 103. A 25.5-g aluminum block is warmed to 65.4 °C...Ch. 6 - Prob. 104E Ch. 6 - Prob. 105E Ch. 6 - Prob. 106E Ch. 6 - 107. Derive a relationship between ΔH and ΔE for a...Ch. 6 - Prob. 108E Ch. 6 - Prob. 109E Ch. 6 - Prob. 110E Ch. 6 - Prob. 111E Ch. 6 - 112. When 10.00 g of phosphorus is burned in O2(g)...Ch. 6 - 113. The ?H for the oxidation of sulfur in the gas...Ch. 6 - 114. The of TiI3(s) is –328 kJ/mol and the ΔH°...Ch. 6 - Prob. 115E Ch. 6 - Prob. 116E Ch. 6 - Prob. 117E Ch. 6 - 118. A pure gold ring and a pure silver ring have...Ch. 6 - Prob. 119E Ch. 6 - Prob. 120E Ch. 6 - Prob. 121E Ch. 6 - Prob. 122E Ch. 6 - Prob. 123E Ch. 6 - Prob. 124E Ch. 6 - Prob. 125E Ch. 6 - Prob. 126E Ch. 6 - Prob. 127E Ch. 6 - Prob. 128E Ch. 6 - Prob. 129E Ch. 6 - Prob. 130E Ch. 6 - 131. Which statement is true of the internal...Ch. 6 - Prob. 132E Ch. 6 - 133. Which expression describes the heat evolved...Ch. 6 - Prob. 134E Ch. 6 - 135. A 1-kg cylinder of aluminum and 1-kg jug of...Ch. 6 - Prob. 136E Ch. 6 - 137. When 1 mol of a gas burns at constant...Ch. 6 - Prob. 138E Ch. 6 - Prob. 139E

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