Chapter 6, Problem 42IP

(a)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(b)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(c)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(d)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(e)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(f)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(g)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(h)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(i)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(j)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration

(k)

Interpretation Introduction

Interpretation:

For the given reaction mechanism, position of equilibrium, transition state, $\text{ΔΗ}$ (Enthalpy), $\text{ΔS}$ (Entropy) and $\text{ΔG}$ (Gibbs free energy) and order of the reaction should be identified

Concept introduction:

When the heat energy was absorbed by the system from the surrounding is called endothermic reaction

When heat energy or light energy was unconfined to the surrounding from the system is called exothermic reaction.

$\text{ΔS}$ (Entropy) can be identified by using formula.

$\text{ΔS = Number of products – Number of reactant}$

General formula to calculate the Gibbs free energy is $\text{ΔG = ΔΗ –TΔS}$

First order reaction a first-order reaction is the rate of the reaction which depends on only one reactant concentration

Second order reaction: Second Order Reactions are characterized by the property of the rate of the reaction is depends on two reactant concentration