ORGANIC CHEMISTRY-ETEXT REG ACCESS
ORGANIC CHEMISTRY-ETEXT REG ACCESS
12th Edition
ISBN: 9781119308362
Author: Solomons
Publisher: WILEY
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Chapter 6, Problem 3PP
Interpretation Introduction

Interpretation:

The net ionic equations are to be written, and the nucleophile, substrate, and leaving group are to be designated in the given equations.

Concept introduction:

Nucleophilic substitution is a reaction in which an electron-rich group, called a nucleophile, substitutes an outgoing group on a saturated carbon atom. The group that is replaced carries the bonding electron pair with it and is called the leaving group. Nucleophilic substitution reactions are of two types- when the order of the reaction is first order it is represented as Sn1 ands when the order is of second order then represented as Sn2.

Spectator ions are ions that are present on both sides of the equation and neither undergo any change nor are involved in covalent bonding.

A net ionic equation is the ionic equation with no spectator ions.

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1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br O
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