CHEMISTRY
2nd Edition
ISBN: 9781593995782
Author: OpenStax
Publisher: XANEDU PUBLISHING
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Textbook Question
Chapter 6, Problem 33E
Describe the properties of an electron associated with each of the following four quantum numbers:
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
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Chapter 6 Solutions
CHEMISTRY
Ch. 6 - The light produced by a red neon sign is due to...Ch. 6 - An FM radio station found at 103.1 on the FM dial...Ch. 6 - FM-95, an FM radio station, broadcasts at a...Ch. 6 - A bright violet line occurs at 435.8 nm in the...Ch. 6 - Light with a wavelength of 614.5 nm looks orange....Ch. 6 - Heated lithium atoms emit photons of light with an...Ch. 6 - A photon of light produced by a surgical laser has...Ch. 6 - When rubidium ions are heated to a high...Ch. 6 - The emission spectrum of cesium contains two lines...Ch. 6 - Photons of infrared radiation are responsible for...
Ch. 6 - One of the radiographic devices used in a...Ch. 6 - The eyes of certain reptiles pass a single visual...Ch. 6 - RGB color television and computer displays use...Ch. 6 - Answer the following questions about a Blu-ray...Ch. 6 - What is the threshold frequency for sodium metal...Ch. 6 - Why is the electron in a Bohr hydrogen atom bound...Ch. 6 - What does it mean to say that the energy of the...Ch. 6 - Using the Bohr model, determine the energy, in...Ch. 6 - The electron volt (eV) is a convenient unit of...Ch. 6 - Using the Bohr model, determine the lowest...Ch. 6 - Using the Bohr model, determine the lowest...Ch. 6 - Using the Bohr model, determine the energy of an...Ch. 6 - Using the Bohr model, determine the energy of an...Ch. 6 - How far from the nucleus in angstroms (1 angstrom...Ch. 6 - What is the radius, in angstroms, of the orbital...Ch. 6 - Using the Bohr model, determine the energy in...Ch. 6 - Using the Bohr model, determine the energy in...Ch. 6 - Consider a large number of hydrogen atoms with...Ch. 6 - How are the Bohr model and the Rutherford model of...Ch. 6 - The spectra of hydrogen and of calcium are shown...Ch. 6 - How are the Bohr model and the quantum mechanical...Ch. 6 - What are the allowed values for each of the four...Ch. 6 - Describe the properties of an electron associated...Ch. 6 - Answer the following questions: (a) Without using...Ch. 6 - Identify the subshell in which electrons with the...Ch. 6 - Which of the subshells described in the previous...Ch. 6 - Identify the subshell in which electrons with the...Ch. 6 - Which of the subshells described in the previous...Ch. 6 - Sketch the boundary surface of a dx2y2 and a py...Ch. 6 - Sketch the px and dxz orbitals. Be sure to show...Ch. 6 - Consider the orbitals shown here in outline. (a)...Ch. 6 - State the Heisenberg uncertainty principle....Ch. 6 - How many electrons could be held in the second...Ch. 6 - Which of the following equations describe...Ch. 6 - Write a set of quantum numbers for each of the...Ch. 6 - Read the labels of several commercial products and...Ch. 6 - Read the labels of several commercial products and...Ch. 6 - Using complete subshell notation (not...Ch. 6 - Using complete subshell notation ( 1s22s22p6, and...Ch. 6 - Is 1s22s22p6 the symbol for a macroscopic property...Ch. 6 - What additional information do we need to answer...Ch. 6 - Draw the orbital diagram for the valence shell of...Ch. 6 - Use an orbital diagram to describe the electron...Ch. 6 - Using complete subshell notation ( 1s22s22p6, and...Ch. 6 - Which atom has the electron configuration...Ch. 6 - Which atom has the electron configuration...Ch. 6 - Which ion with a +1 charge has the electron...Ch. 6 - Which of the following atoms contains only three...Ch. 6 - Which of the following has two unpaired electrons?...Ch. 6 - Which atom would be expected to have a half-filled...Ch. 6 - Which atom would be expected to have a half-filled...Ch. 6 - In one area of Australia, the cattle did not...Ch. 6 - Thallium was used as a poison in the Agatha...Ch. 6 - Write the electron configurations for the...Ch. 6 - Cobalt60 and iodine131 are radioactive isotopes...Ch. 6 - Write a set of quantum numbers for each of the...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Atoms of which group in the periodic table have a...Ch. 6 - Atoms of which group in the periodic table have a...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - List the following ions in order of increasing...Ch. 6 - Which atom and/or ion is (are) isoelectronic with...Ch. 6 - Which of the following atoms and ions is (are)...Ch. 6 - Compare both the numbers of protons and electrons...Ch. 6 - Of the five elements Al, Cl, I, Na, Rb, which has...Ch. 6 - Of the five elements Sn, Si, Sb, O, Te, which has...Ch. 6 - The ionic radii of the ions S2, Cl, and K+ are...Ch. 6 - Which main group atom would be expected to have...Ch. 6 - Explain why Al is a member of group 13 rather than...
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