The increasing stability of carbocation is to be interpreted. Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is: Tertiary >Secondary >Primary

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Answer 1

Question

Chapter 6, Problem 28PP

(a)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

(b)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

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man Campus Depa (a) Draw the three products (constitutional isomers) obtained when 2-methyl-3-hexene reacts with water and a trace of H2SO4. Hint: one product forms as the result of a 1,2-hydride shift. (1.5 pts) This is the acid-catalyzed alkene hydration reaction.

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. • • Use retrosynthesis to design a synthesis Br OH

Answer 2

Question

Chapter 6, Problem 28PP

(a)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

(b)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

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Answer 3

Question

Chapter 6, Problem 28PP

(a)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

(b)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

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Answer 4

Question

Chapter 6, Problem 28PP

(a)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

(b)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

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Answer 5

Chapter 6, Problem 28PP

(a)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

(b)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

Answer 6

Chapter 6, Problem 28PP

(a)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

Answer 7

Chapter 6, Problem 28PP

(a)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

Answer 8

(b)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

Answer 9

(b)

Interpretation Introduction

Interpretation: The increasing stability of carbocation is to be interpreted.

Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:

Tertiary >Secondary >Primary

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 6.1 - Prob. 1LTS Ch. 6.1 - Prob. 1PTS Ch. 6.1 - Prob. 2ATS Ch. 6.2 - Prob. 3CC Ch. 6.3 - Prob. 4CC Ch. 6.3 - Prob. 5CC Ch. 6.4 - Prob. 6CC Ch. 6.6 - Prob. 7CC Ch. 6.7 - Prob. 2LTS Ch. 6.7 - Prob. 8PTS

Solution Summary: The author explains how intermediates like carbocation can rearrange to give more stable, based on hyperconjugation and inductive effect.

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